High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System

Olga B. Lapina; Viktor V. Terskikh; Aleksander A. Shubin; V.M Mastikhin; Kim Michael Eriksen; Rasmus Fehrmann

doi:10.1021/jp971789b

High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System

Olga B. Lapina, Viktor V. Terskikh, Aleksander A. Shubin, V.M Mastikhin, Kim Michael Eriksen, Rasmus Fehrmann

Department of Chemistry

RAS - Boreskov Institute of Catalysis, Siberian Branch

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.

Original language	English
Journal	Journal of Physical Chemistry B
Volume	101
Issue number	45
Pages (from-to)	9188-9194
ISSN	1520-6106
DOIs	https://doi.org/10.1021/jp971789b
Publication status	Published - 1997

Access to Document

10.1021/jp971789b

OpenUrl availability

Full text

Cite this

@article{b1608a067c71480894b90e5c0c6ad445,

title = "High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System",

abstract = "133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.",

author = "Lapina, \{Olga B.\} and Terskikh, \{Viktor V.\} and Shubin, \{Aleksander A.\} and V.M Mastikhin and Eriksen, \{Kim Michael\} and Rasmus Fehrmann",

year = "1997",

doi = "10.1021/jp971789b",

language = "English",

volume = "101",

pages = "9188--9194",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

publisher = "American Chemical Society",

number = "45",

}

TY - JOUR

T1 - High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System

AU - Lapina, Olga B.

AU - Terskikh, Viktor V.

AU - Shubin, Aleksander A.

AU - Mastikhin, V.M

AU - Eriksen, Kim Michael

AU - Fehrmann, Rasmus

PY - 1997

Y1 - 1997

N2 - 133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.

AB - 133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.

U2 - 10.1021/jp971789b

DO - 10.1021/jp971789b

M3 - Journal article

SN - 1520-6106

VL - 101

SP - 9188

EP - 9194

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 45

ER -