High Temperature NMR Studies of the Glass-Crystal Transition in the Cs2S2O7-V2O5 System

Olga B. Lapina, Viktor V. Terskikh, Aleksander A. Shubin, V.M Mastikhin, Kim Michael Eriksen, Rasmus Fehrmann

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133Cs and 51V NMR spectra have been recorded of Cs2S2O7 and the catalytically important Cs2S2O7-V2O5 mixtures in the temperature range 20 - 550 C. A high mobility of Cs+ in the solid Cs2S2O7 was observed. The transformation from glassy state to crystalline state was investigated for the compositions Cs/V = 1, 2 and 4.
Original languageEnglish
JournalJournal of Physical Chemistry B
Issue number45
Pages (from-to)9188-9194
Publication statusPublished - 1997

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