Abstract
In order to select the most suitable ionic liquids (ILs) for certain applications it is necessary to know some of their thermophysical properties, such as density or viscosity. In this work we have performed density measurements of two ILs 1-ethyl-3-methylimidazolium ethylsulfate and 1-(2-methoxyethyl)-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl)imide in a broad range of temperature and pressure ((278.15 to 398.15) K and up to 120 MPa). From these measurements we have obtained other volumetric properties such as isothermal compressibility and isobaric thermal expansivity. In addition, density values were predicted using the method proposed by Gardas and Coutinho and also that proposed by Jacquemin et al., obtaining a good agreement with experimental values. (C) 2012 Elsevier Ltd. All rights reserved.
| Original language | English |
|---|---|
| Journal | JOURNAL OF CHEMICAL THERMODYNAMICS |
| Volume | 48 |
| Pages (from-to) | 213-220 |
| ISSN | 0021-9614 |
| DOIs | |
| Publication status | Published - 2012 |
| Externally published | Yes |
Keywords
- Density (specific gravity)
- Pressure
- Thermodynamic properties
- Volumetric analysis
- Ionic liquids
- Density value
- Experimental values
- High pressure
- Isothermal compressibility
- Thermal expansion coefficient
- Thermal expansivity
- Volumetric properties
- Density
- Ionic liquid
- THERMODYNAMICS
- CHEMISTRY,
- IONIC LIQUID PROPERTIES
- BINARY-MIXTURES
- SURFACE-TENSION
- THERMOPHYSICAL PROPERTIES
- DENSITY-MEASUREMENTS
- INFINITE DILUTION
- REFRACTIVE-INDEX
- EXCESS VOLUMES
- CARBON-DIOXIDE
- N-ALKANES