High pressure CO hydrogenation over bimetallic Pt-Co catalysts

Jakob Munkholt Christensen; Andrew James Medford; Felix Studt; Anker Degn Jensen

doi:10.1007/s10562-014-1220-x

High pressure CO hydrogenation over bimetallic Pt-Co catalysts

Jakob Munkholt Christensen
, Andrew James Medford
, Felix Studt
, Anker Degn Jensen

SLAC National Accelerator Laboratory

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The potential of bimetallic Pt-Co catalysts for production of higher alcohols in high pressure CO hydrogenation has been assessed. Two catalysts (Pt3Co/SiO2 and PtCo/SiO2) were tested, and the existing literature on CO hydrogenation over Pt-Co catalysts was reviewed. It is found that the catalysts produce mainly methanol in the Pt-rich composition range andmainly hydrocarbons (and to a modest extent higher alcohols) in the Co-rich composition range. The transition between the two types of behavior occurs in a narrow composition range around a molar Pt:Co ratio of 1:1.

Original language	English
Journal	Catalysis Letters
Volume	144
Issue number	5
Pages (from-to)	777-782
ISSN	1011-372X
DOIs	https://doi.org/10.1007/s10562-014-1220-x
Publication status	Published - 2014

Keywords

Catalysis
Chemistry (all)
CO hydrogenation
Cobalt
Higher alcohols
Hydrocarbons
Methanol
Platinum
Catalysts
Hydrogenation
Composition ranges
High pressure CO

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title = "High pressure CO hydrogenation over bimetallic Pt-Co catalysts",

abstract = "The potential of bimetallic Pt-Co catalysts for production of higher alcohols in high pressure CO hydrogenation has been assessed. Two catalysts (Pt3Co/SiO2 and PtCo/SiO2) were tested, and the existing literature on CO hydrogenation over Pt-Co catalysts was reviewed. It is found that the catalysts produce mainly methanol in the Pt-rich composition range andmainly hydrocarbons (and to a modest extent higher alcohols) in the Co-rich composition range. The transition between the two types of behavior occurs in a narrow composition range around a molar Pt:Co ratio of 1:1.",

keywords = "Catalysis, Chemistry (all), CO hydrogenation, Cobalt, Higher alcohols, Hydrocarbons, Methanol, Platinum, Catalysts, Hydrogenation, Composition ranges, High pressure CO",

author = "Christensen, \{Jakob Munkholt\} and Medford, \{Andrew James\} and Felix Studt and Jensen, \{Anker Degn\}",

year = "2014",

doi = "10.1007/s10562-014-1220-x",

language = "English",

volume = "144",

pages = "777--782",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "5",

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TY - JOUR

T1 - High pressure CO hydrogenation over bimetallic Pt-Co catalysts

AU - Christensen, Jakob Munkholt

AU - Medford, Andrew James

AU - Studt, Felix

AU - Jensen, Anker Degn

PY - 2014

Y1 - 2014

N2 - The potential of bimetallic Pt-Co catalysts for production of higher alcohols in high pressure CO hydrogenation has been assessed. Two catalysts (Pt3Co/SiO2 and PtCo/SiO2) were tested, and the existing literature on CO hydrogenation over Pt-Co catalysts was reviewed. It is found that the catalysts produce mainly methanol in the Pt-rich composition range andmainly hydrocarbons (and to a modest extent higher alcohols) in the Co-rich composition range. The transition between the two types of behavior occurs in a narrow composition range around a molar Pt:Co ratio of 1:1.

AB - The potential of bimetallic Pt-Co catalysts for production of higher alcohols in high pressure CO hydrogenation has been assessed. Two catalysts (Pt3Co/SiO2 and PtCo/SiO2) were tested, and the existing literature on CO hydrogenation over Pt-Co catalysts was reviewed. It is found that the catalysts produce mainly methanol in the Pt-rich composition range andmainly hydrocarbons (and to a modest extent higher alcohols) in the Co-rich composition range. The transition between the two types of behavior occurs in a narrow composition range around a molar Pt:Co ratio of 1:1.

KW - Catalysis

KW - Chemistry (all)

KW - CO hydrogenation

KW - Cobalt

KW - Higher alcohols

KW - Hydrocarbons

KW - Methanol

KW - Platinum

KW - Catalysts

KW - Hydrogenation

KW - Composition ranges

KW - High pressure CO

U2 - 10.1007/s10562-014-1220-x

DO - 10.1007/s10562-014-1220-x

M3 - Journal article

SN - 1011-372X

VL - 144

SP - 777

EP - 782

JO - Catalysis Letters

JF - Catalysis Letters

IS - 5

ER -

High pressure CO hydrogenation over bimetallic Pt-Co catalysts

Abstract

Keywords

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