TY - JOUR

T1 - Heat capacity and Joule-Thomson coefficient of selected n-alkanes at 0.1 and 10 MPa in broad temperature ranges

AU - Regueira Muñiz, Teresa

AU - Varzandeh, Farhad

AU - Stenby, Erling Halfdan

AU - Yan, Wei

PY - 2017

Y1 - 2017

N2 - Isobaric heat capacity of six n-alkanes, i.e. n-hexane, n-octane, n-decane, n-dodecane, n-tetradecane and n-hexadecane, was determined with a Calvet type differential heat-flux calorimeter at 0.1 and 10 MPa in a broad temperature range. The measured isobaric heat capacity data were combined with the literature density data for these n-alkanes to determine the corresponding Joule-Thomson coefficients. Four different EoSs, Soave-Redlich-Kwong, Peng-Robinson, Perturbed Chain Statistical Associating Fluid Theory, and Soave-Benedict-Webb-Rubin, were used to model the heat capacities and Joule-Thomson coefficients. Moreover, the Joule-Thomson inversion curves for these n-alkanes were also calculated by the four EoSs.

AB - Isobaric heat capacity of six n-alkanes, i.e. n-hexane, n-octane, n-decane, n-dodecane, n-tetradecane and n-hexadecane, was determined with a Calvet type differential heat-flux calorimeter at 0.1 and 10 MPa in a broad temperature range. The measured isobaric heat capacity data were combined with the literature density data for these n-alkanes to determine the corresponding Joule-Thomson coefficients. Four different EoSs, Soave-Redlich-Kwong, Peng-Robinson, Perturbed Chain Statistical Associating Fluid Theory, and Soave-Benedict-Webb-Rubin, were used to model the heat capacities and Joule-Thomson coefficients. Moreover, the Joule-Thomson inversion curves for these n-alkanes were also calculated by the four EoSs.

KW - n-alkane

KW - Heat capacity

KW - Joule-Thomson coefficient

KW - High pressure

KW - High temperature

U2 - 10.1016/j.jct.2017.03.034

DO - 10.1016/j.jct.2017.03.034

M3 - Journal article

SN - 0021-9614

VL - 111

SP - 250

EP - 264

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

ER -