Hard, charged spheres in spherical pores. Grand canonical ensemble Monte Carlo calculations

Peter Sloth, T. S. Sørensen

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    Abstract

    A model consisting of hard charged spheres inside hard spherical pores is investigated by grand canonical ensemble Monte Carlo calculations. It is found that the mean ionic density profiles in the pores are almost the same when the wall of the pore is moderately charged as when it is uncharged. Also, a bulklike phase is found to be present at the center of the pores in surprisingly small systems. Finally, the Poisson–Boltzman approximation is discussed in the light of our Monte Carlo results. The Journal of Chemical Physics is copyrighted by The American Institute of Physics.
    Original languageEnglish
    JournalJournal of Chemical Physics
    Volume96
    Issue number1
    Pages (from-to)548-554
    ISSN0021-9606
    DOIs
    Publication statusPublished - 1992

    Bibliographical note

    Copyright (1992) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics

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