Gold micro- and nano-particles for surface enhanced vibrational spectroscopy of pyridostigmine bromide

Leonid Dolgov; Olena Fesenko; Vladyslav Kavelin; Oksana Budnyk; Victorio Estrela-Llopis; Alona Chevychalova; Taavi Repän; Vladimir I. Kondratiev; Sergii Mamykin

doi:10.1016/j.vibspec.2016.11.005

Gold micro- and nano-particles for surface enhanced vibrational spectroscopy of pyridostigmine bromide

Leonid Dolgov, Olena Fesenko, Vladyslav Kavelin, Oksana Budnyk, Victorio Estrela-Llopis, Alona Chevychalova, Taavi Repän, Vladimir I. Kondratiev, Sergii Mamykin

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Abstract

Triangular gold microprisms and spherical silica nanoparticles with attached gold nano-islands were examined as an active nanostructures for the surface enhanced Raman and infrared spectroscopy. These particles were probed for the detection of pyridostigmine bromide as a safe analog of military compound sarin. Raman and infrared spectral bands of the pyridostigmine bromide were measured. Detailed correlation of obtained spectral bands with specific vibrations in pyridostigmine bromide was done. Silica nanoparticles with attached gold nano-islands showed more essential enhancement of the Raman signal than gold microcrystals. The reasons of such behaviour are discussed.

Original language	English
Journal	Vibrational Spectroscopy
Volume	88
Pages (from-to)	71-76
ISSN	0924-2031
DOIs	https://doi.org/10.1016/j.vibspec.2016.11.005
Publication status	Published - 2017

Keywords

Spectroscopy
Gilded nanoparticles
Pyridostigmine bromide
SEIRA
SERS
Gold
Infrared spectroscopy
Nanostructures
Raman spectroscopy
Silica
Infrared spectral bands
Micro and nano-particle
Silica nanoparticles
Spherical silica
Surface enhanced Raman
Nanoparticles

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10.1016/j.vibspec.2016.11.005

Dolgov revised text with figuresAccepted author manuscript, 1.17 MBLicence: CC BY-NC-ND

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title = "Gold micro- and nano-particles for surface enhanced vibrational spectroscopy of pyridostigmine bromide",

abstract = "Triangular gold microprisms and spherical silica nanoparticles with attached gold nano-islands were examined as an active nanostructures for the surface enhanced Raman and infrared spectroscopy. These particles were probed for the detection of pyridostigmine bromide as a safe analog of military compound sarin. Raman and infrared spectral bands of the pyridostigmine bromide were measured. Detailed correlation of obtained spectral bands with specific vibrations in pyridostigmine bromide was done. Silica nanoparticles with attached gold nano-islands showed more essential enhancement of the Raman signal than gold microcrystals. The reasons of such behaviour are discussed.",

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author = "Leonid Dolgov and Olena Fesenko and Vladyslav Kavelin and Oksana Budnyk and Victorio Estrela-Llopis and Alona Chevychalova and Taavi Rep{\"a}n and Kondratiev, {Vladimir I.} and Sergii Mamykin",

year = "2017",

doi = "10.1016/j.vibspec.2016.11.005",

language = "English",

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pages = "71--76",

journal = "Vibrational Spectroscopy",

issn = "0924-2031",

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T1 - Gold micro- and nano-particles for surface enhanced vibrational spectroscopy of pyridostigmine bromide

AU - Dolgov, Leonid

AU - Fesenko, Olena

AU - Kavelin, Vladyslav

AU - Budnyk, Oksana

AU - Estrela-Llopis, Victorio

AU - Chevychalova, Alona

AU - Repän, Taavi

AU - Kondratiev, Vladimir I.

AU - Mamykin, Sergii

PY - 2017

Y1 - 2017

N2 - Triangular gold microprisms and spherical silica nanoparticles with attached gold nano-islands were examined as an active nanostructures for the surface enhanced Raman and infrared spectroscopy. These particles were probed for the detection of pyridostigmine bromide as a safe analog of military compound sarin. Raman and infrared spectral bands of the pyridostigmine bromide were measured. Detailed correlation of obtained spectral bands with specific vibrations in pyridostigmine bromide was done. Silica nanoparticles with attached gold nano-islands showed more essential enhancement of the Raman signal than gold microcrystals. The reasons of such behaviour are discussed.

AB - Triangular gold microprisms and spherical silica nanoparticles with attached gold nano-islands were examined as an active nanostructures for the surface enhanced Raman and infrared spectroscopy. These particles were probed for the detection of pyridostigmine bromide as a safe analog of military compound sarin. Raman and infrared spectral bands of the pyridostigmine bromide were measured. Detailed correlation of obtained spectral bands with specific vibrations in pyridostigmine bromide was done. Silica nanoparticles with attached gold nano-islands showed more essential enhancement of the Raman signal than gold microcrystals. The reasons of such behaviour are discussed.

KW - Spectroscopy

KW - Gilded nanoparticles

KW - Pyridostigmine bromide

KW - SEIRA

KW - SERS

KW - Gold

KW - Infrared spectroscopy

KW - Nanostructures

KW - Raman spectroscopy

KW - Silica

KW - Infrared spectral bands

KW - Micro and nano-particle

KW - Silica nanoparticles

KW - Spherical silica

KW - Surface enhanced Raman

KW - Nanoparticles

U2 - 10.1016/j.vibspec.2016.11.005

DO - 10.1016/j.vibspec.2016.11.005

M3 - Journal article

SN - 0924-2031

VL - 88

SP - 71

EP - 76

JO - Vibrational Spectroscopy

JF - Vibrational Spectroscopy

ER -

Gold micro- and nano-particles for surface enhanced vibrational spectroscopy of pyridostigmine bromide

Abstract

Keywords

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