Formic acid dehydrogenation catalysed by a novel amino-di(N-heterocyclic carbene) based Ru-CNC pincer complex

Patricia Aufricht; Valeria Nori; Brenda Rabell; Luca Piccirilli; Sakhitha Koranchalil; René W. Larsen; Mathias T. Nielsen; Martin Nielsen

doi:10.1039/d4cc05164e

Formic acid dehydrogenation catalysed by a novel amino-di(N-heterocyclic carbene) based Ru-CNC pincer complex

Patricia Aufricht, Valeria Nori, Brenda Rabell, Luca Piccirilli, Sakhitha Koranchalil, René W. Larsen, Mathias T. Nielsen^*, Martin Nielsen^*

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A new Ru(ii) complex featuring a novel amino-di(N-heterocyclic carbene) CNC pincer ligand, ^iPrCNC-RuCl₂(CO) (Ru-1), has been developed and characterised in depth. Ru-1 forms an efficient and durable catalytic formic acid dehydrogenation system in combination with the ionic liquid 1-ethyl-3-methylimidazolium diethylphosphate (EMIM PO₂(OEt)₂).

Original language	English
Journal	Chemical Communications
Volume	61
Issue number	20
Pages (from-to)	3986-3989
ISSN	1359-7345
DOIs	https://doi.org/10.1039/d4cc05164e
Publication status	Published - 2025

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title = "Formic acid dehydrogenation catalysed by a novel amino-di(N-heterocyclic carbene) based Ru-CNC pincer complex",

abstract = "A new Ru(ii) complex featuring a novel amino-di(N-heterocyclic carbene) CNC pincer ligand, iPrCNC-RuCl2(CO) (Ru-1), has been developed and characterised in depth. Ru-1 forms an efficient and durable catalytic formic acid dehydrogenation system in combination with the ionic liquid 1-ethyl-3-methylimidazolium diethylphosphate (EMIM PO2(OEt)2).",

author = "Patricia Aufricht and Valeria Nori and Brenda Rabell and Luca Piccirilli and Sakhitha Koranchalil and \{W. Larsen\}, Ren{\'e} and Nielsen, \{Mathias T.\} and Martin Nielsen",

note = "Publisher Copyright: {\textcopyright} 2025 The Royal Society of Chemistry.",

year = "2025",

doi = "10.1039/d4cc05164e",

language = "English",

volume = "61",

pages = "3986--3989",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Formic acid dehydrogenation catalysed by a novel amino-di(N-heterocyclic carbene) based Ru-CNC pincer complex

AU - Aufricht, Patricia

AU - Nori, Valeria

AU - Rabell, Brenda

AU - Piccirilli, Luca

AU - Koranchalil, Sakhitha

AU - W. Larsen, René

AU - Nielsen, Mathias T.

AU - Nielsen, Martin

PY - 2025

Y1 - 2025

N2 - A new Ru(ii) complex featuring a novel amino-di(N-heterocyclic carbene) CNC pincer ligand, iPrCNC-RuCl2(CO) (Ru-1), has been developed and characterised in depth. Ru-1 forms an efficient and durable catalytic formic acid dehydrogenation system in combination with the ionic liquid 1-ethyl-3-methylimidazolium diethylphosphate (EMIM PO2(OEt)2).

AB - A new Ru(ii) complex featuring a novel amino-di(N-heterocyclic carbene) CNC pincer ligand, iPrCNC-RuCl2(CO) (Ru-1), has been developed and characterised in depth. Ru-1 forms an efficient and durable catalytic formic acid dehydrogenation system in combination with the ionic liquid 1-ethyl-3-methylimidazolium diethylphosphate (EMIM PO2(OEt)2).

U2 - 10.1039/d4cc05164e

DO - 10.1039/d4cc05164e

M3 - Journal article

C2 - 39820207

AN - SCOPUS:85215829668

SN - 1359-7345

VL - 61

SP - 3986

EP - 3989

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Formic acid dehydrogenation catalysed by a novel amino-di(N-heterocyclic carbene) based Ru-CNC pincer complex

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