Abstract
We review the past and current efforts towards interesting molecular, magnetic systems encompassing inter-metallic fluoride bridging. The efficacy of fluoride as mediator of magnetic interactions is addressed and the use of the structure-directing properties of the fluoride ion as a synthetic handle for polymetallic systems is established. Finally, the magnetic properties of selected examples of systems of increasing complexity are discussed.
Original language | English |
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Journal | Coordination Chemistry Reviews |
Volume | 299 |
Pages (from-to) | 1-21 |
ISSN | 0010-8545 |
DOIs | |
Publication status | Published - 2015 |
Externally published | Yes |