Fate and Cotransport of Pb(II) and Cd(II) Heavy Ions with Bentonite Colloidal Flow in Saturated Porous Media

This study examines the transport and retention of colloidal particles and heavy ions in porous sand, focusing on the environmental risks associated with waste from oil and gas drilling. Experimental and numerical models assess the influence of flow rate, external filter cake layer, and ionic strength on bentonite clay particles and heavy ions, such as cadmium (Cd) and lead (Pb), in near-wellbore (high-flux) and far-field (low-flux) scenarios. Colloidal filtration theory and the one-dimensional convection-dispersion equation with two-site kinetic model for attachment and detachment were utilized to calibrate and predict the transport of colloidal suspension in porous media. The research investigates the role of internal and external filter cakes on sand column pressure distribution and heavy ion absorption. Results indicate that the mobility of colloids and heavy ions is influenced by the ionic strength and pH of the carrying fluid. Colloidal clay suspensions show a higher affinity for Pb (II) absorption, while Cd (II) exhibits increased mobility in both clean sand and colloidal environments. Notably, the formation of an external filter cake significantly delays the breakthrough of heavy ions, up to four times longer than in clean sand, and reduces Cd (II) and Pb (II) outlet concentrations by 86% and 93%, respectively. This cake also limits clay concentration and particle size passage. High clay concentrations or injections under high ionic conditions induce clay bridging in pore throats, enhancing internal filtration and heavy ion retention.
Conversely, low clay fluxes allow freer particle passage, increasing heavy ion loads and outlet concentrations.