Fast Switching ITO Free Electrochromic Devices

Jacob Jensen, Markus Hösel, Inyoung Kim, Jong-Su Yu, Jeongdai Jo, Frederik C Krebs

Research output: Contribution to journalJournal articleResearchpeer-review


Indium-doped tin oxide free electrochromic devices are prepared by coating electrochromic polymers onto polyethylene terephthalate substrates encompassing two different silver grids as electrodes. One design comprises a fl exoprinted highly conductive silver grid electrode, yielding electrochromic devices with a response time of 2 s for an optical contrast of 27%. The other design utilizes an embedded silver grid electrode whereupon response times of 0.5 s for a 30% optical contrast are realized when oxidizing the device. A commercially available conductive poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate acid) formulation (PEDOT:PSS) is coated onto the silver grids as a charge balancing polymer, and is in this setting found to be superior to a polypyrrole previously employed in electrochromic devices. In addition, the PEDOT:PSS layer increases the conductivity in the hexagonal grid structure.
Original languageEnglish
JournalAdvanced Functional Materials
Pages (from-to)1228-1233
Publication statusPublished - 2014

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