Fast Resonance Raman Spectroscopy of Short-Lived Radicals

Palle Bjørn Pagsberg, Robert Walter Wilbrandt, Karina Benthin Hansen, Knud-Vilhelm Weisberg

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    We report the first application of pulsed resonance Raman spectroscopy to the study of short-lived free radicals produced by pulse radiolysis. A single pulse from a flash-lamp pumped tunable dye laser is used to excite the resonance Raman spectrum of the p-terphenyl anion radical with an initial concentration of 4 × 10−5 moles per liter and a half life of 2 μs. The spectrum is recorded by an optical multichannel system consisting of an image intensifier coupled to a TV-camera.
    Original languageEnglish
    JournalChemical Physics Letters
    Volume39
    Issue number3
    Pages (from-to)538-541
    ISSN0009-2614
    DOIs
    Publication statusPublished - 1976

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