Fast Pyrolysis of Lignin Using a Pyrolysis Centrifuge Reactor

Ngoc Trung Trinh, Peter Arendt Jensen, Zsuzsa Sárossy, Kim Dam-Johansen, Niels Ole Knudsen, Hanne Risbjerg Sørensen, Helge Egsgaard

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Fast pyrolysis of lignin from an ethanol plant was investigated on a lab scale pyrolysis centrifuge reactor (PCR) with respect to pyrolysis temperature, reactor gas residence time, and feed rate. A maximal organic oil yield of 34 wt % dry basis (db) (bio-oil yield of 43 wt % db) is obtained at temperatures of 500−550 °C, reactor gas residence time of 0.8 s, and feed rate of 5.6 g/min. Gas chromatography mass spectrometry and size-exclusion chromatography were used to characterize the Chemical properties of the lignin oils. Acetic acid, levoglucosan, guaiacol, syringols, and p-vinylguaiacol are found to be major chemical components in the lignin oil. The maximal yields of 0.62, 0.67, and 0.38 wt % db were obtained for syringol, p-vinylguaiacol, and guaiacol, respectively. The reactor temperature effect was investigated in a range of 450−600 °C and has a considerable effect on the observed chemical components and molecular mass distribution of the lignin oils. The obtained lignin oil has a very different components composition when compared to a beech wood oil.
Original languageEnglish
JournalEnergy & Fuels
Volume27
Pages (from-to)3802−3810
Number of pages9
ISSN0887-0624
DOIs
Publication statusPublished - 2013

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