Facile method to synthesis hybrid phase 1T@2H MoSe2 nanostructures for rechargeable lithium ion batteries

Dhanasekaran Vikraman, Sajjad Hussain, K. Prasanna, K. Karuppasamy, Jongwan Jung, Hyun-Seok Kim*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

Energy storage devices have become vital parts of our routine life. Among the numerous candidates, lithium ion batteries are considered the most favorable energy storage systems. MoSe2 consists of Se–Mo–Se atom layers bounded with van-der Waals forces and is highly favored for lithium ion intercalation and extraction. This paper establishes a simple and economical one-pot chemical method to synthesize MoSe2 nanostructures for lithium ion battery anode material. Raman scattering confirmed the 1T@2H MoSe2 mixed phase structure, transmission electron microscopy showed 2H and 1T phase contours in the MoSe2 nanosheet, and scanning electron microscopy showed the nanograin honeycomb structured morphology. The 1T@2H MoSe2 nanostructures deliver enhanced primary discharge capacity 843 mAh/g at 100 mA/g with 99% Coulombic efficiency after 100 cycles. Electrochemical results confirmed the 1T@2H MoSe2 nanostructure would be an excellent anode material and a promising candidate for high performance lithium ion batteries.
Original languageEnglish
JournalJournal of Electroanalytical Chemistry
Volume833
Pages (from-to)333-339
ISSN1572-6657
DOIs
Publication statusPublished - 2019

Keywords

  • Lithium ion batteries
  • MoSe2
  • 1T @2H phase
  • TEM
  • Raman

Cite this

Vikraman, Dhanasekaran ; Hussain, Sajjad ; Prasanna, K. ; Karuppasamy, K. ; Jung, Jongwan ; Kim, Hyun-Seok. / Facile method to synthesis hybrid phase 1T@2H MoSe2 nanostructures for rechargeable lithium ion batteries. In: Journal of Electroanalytical Chemistry. 2019 ; Vol. 833. pp. 333-339.
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title = "Facile method to synthesis hybrid phase 1T@2H MoSe2 nanostructures for rechargeable lithium ion batteries",
abstract = "Energy storage devices have become vital parts of our routine life. Among the numerous candidates, lithium ion batteries are considered the most favorable energy storage systems. MoSe2 consists of Se–Mo–Se atom layers bounded with van-der Waals forces and is highly favored for lithium ion intercalation and extraction. This paper establishes a simple and economical one-pot chemical method to synthesize MoSe2 nanostructures for lithium ion battery anode material. Raman scattering confirmed the 1T@2H MoSe2 mixed phase structure, transmission electron microscopy showed 2H and 1T phase contours in the MoSe2 nanosheet, and scanning electron microscopy showed the nanograin honeycomb structured morphology. The 1T@2H MoSe2 nanostructures deliver enhanced primary discharge capacity 843 mAh/g at 100 mA/g with 99{\%} Coulombic efficiency after 100 cycles. Electrochemical results confirmed the 1T@2H MoSe2 nanostructure would be an excellent anode material and a promising candidate for high performance lithium ion batteries.",
keywords = "Lithium ion batteries, MoSe2, 1T @2H phase, TEM, Raman",
author = "Dhanasekaran Vikraman and Sajjad Hussain and K. Prasanna and K. Karuppasamy and Jongwan Jung and Hyun-Seok Kim",
year = "2019",
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pages = "333--339",
journal = "Journal of Electroanalytical Chemistry",
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Facile method to synthesis hybrid phase 1T@2H MoSe2 nanostructures for rechargeable lithium ion batteries. / Vikraman, Dhanasekaran; Hussain, Sajjad; Prasanna, K.; Karuppasamy, K.; Jung, Jongwan; Kim, Hyun-Seok.

In: Journal of Electroanalytical Chemistry, Vol. 833, 2019, p. 333-339.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Facile method to synthesis hybrid phase 1T@2H MoSe2 nanostructures for rechargeable lithium ion batteries

AU - Vikraman, Dhanasekaran

AU - Hussain, Sajjad

AU - Prasanna, K.

AU - Karuppasamy, K.

AU - Jung, Jongwan

AU - Kim, Hyun-Seok

PY - 2019

Y1 - 2019

N2 - Energy storage devices have become vital parts of our routine life. Among the numerous candidates, lithium ion batteries are considered the most favorable energy storage systems. MoSe2 consists of Se–Mo–Se atom layers bounded with van-der Waals forces and is highly favored for lithium ion intercalation and extraction. This paper establishes a simple and economical one-pot chemical method to synthesize MoSe2 nanostructures for lithium ion battery anode material. Raman scattering confirmed the 1T@2H MoSe2 mixed phase structure, transmission electron microscopy showed 2H and 1T phase contours in the MoSe2 nanosheet, and scanning electron microscopy showed the nanograin honeycomb structured morphology. The 1T@2H MoSe2 nanostructures deliver enhanced primary discharge capacity 843 mAh/g at 100 mA/g with 99% Coulombic efficiency after 100 cycles. Electrochemical results confirmed the 1T@2H MoSe2 nanostructure would be an excellent anode material and a promising candidate for high performance lithium ion batteries.

AB - Energy storage devices have become vital parts of our routine life. Among the numerous candidates, lithium ion batteries are considered the most favorable energy storage systems. MoSe2 consists of Se–Mo–Se atom layers bounded with van-der Waals forces and is highly favored for lithium ion intercalation and extraction. This paper establishes a simple and economical one-pot chemical method to synthesize MoSe2 nanostructures for lithium ion battery anode material. Raman scattering confirmed the 1T@2H MoSe2 mixed phase structure, transmission electron microscopy showed 2H and 1T phase contours in the MoSe2 nanosheet, and scanning electron microscopy showed the nanograin honeycomb structured morphology. The 1T@2H MoSe2 nanostructures deliver enhanced primary discharge capacity 843 mAh/g at 100 mA/g with 99% Coulombic efficiency after 100 cycles. Electrochemical results confirmed the 1T@2H MoSe2 nanostructure would be an excellent anode material and a promising candidate for high performance lithium ion batteries.

KW - Lithium ion batteries

KW - MoSe2

KW - 1T @2H phase

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KW - Raman

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JO - Journal of Electroanalytical Chemistry

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SN - 1572-6657

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