Extensional flow dynamics of polystyrene melt

Qian Huang, H. K. Rasmussen*

*Corresponding author for this work

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Abstract

A linear polystyrene melt with broad molecular weight distribution (CAS 0993-53-6 from Aldrich) was characterized in extensional flow using a filament stretching rheometer. A series of measurements were performed, including (1) the startup of uniaxial extensional flow until steady state; (2) the strain controlled reversed (i.e., biaxial) flow following the startup of uniaxial flow; and (3) stress relaxation (i.e., keeping the strain unchanged) also following the startup of uniaxial flow. The measurements were compared with the model by Narimissa and Wagner [J. Rheol. 60, 625–636 (2016)]. Good agreements at low extension rates and low strain values were observed. Higher deviations were observed at high rates under steady state conditions as well as during stress relaxation and reversed flow.
Original languageEnglish
JournalJournal of Rheology
Volume63
Issue number5
Pages (from-to)829-835
ISSN0148-6055
DOIs
Publication statusPublished - 2019

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