Exploring the Tilt-Angle Dependence of electron tunneling across Molecular junction of Self-Assembled Alkanethiols

Thomas Frederiksen, C. Munuera, C. Ocal, Mads Brandbyge, Magnus Paulsson, D. Sanchez-Portal, A. Arnau

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Electronic transport mechanisms in molecular junctions are investigated by a combination of first-principles calculations and current−voltage measurements of several well-characterized structures. We study self-assembled layers of alkanethiols grown on Au(111) and form tunnel junctions by contacting the molecular layers with the tip of a conductive force microscope. Measurements done under low-load conditions permit us to obtain reliable tilt-angle and molecular length dependencies of the low-bias conductance through the alkanethiol layers. The observed dependence on tilt-angle is stronger for the longer molecular chains. Our calculations confirm the observed trends and explain them as a result of two mechanisms, namely, a previously proposed intermolecular tunneling enhancement as well as a hitherto overlooked tilt-dependent molecular gate effect.
    Original languageEnglish
    JournalA C S Nano
    Volume3
    Issue number8
    Pages (from-to)2073-2080
    ISSN1936-0851
    DOIs
    Publication statusPublished - 2009

    Cite this

    Frederiksen, T., Munuera, C., Ocal, C., Brandbyge, M., Paulsson, M., Sanchez-Portal, D., & Arnau, A. (2009). Exploring the Tilt-Angle Dependence of electron tunneling across Molecular junction of Self-Assembled Alkanethiols. A C S Nano, 3(8), 2073-2080. https://doi.org/10.1021/nn9000808