Exploring the Reactivity of Thiocarbonyl S-(tert-Alkylimides)

Farag A. G. El-Essawy, Ahmed F. Khattab, Salah M. Yassin, Ibrahim A. El-Sakka, Jørgen Øgaard Madsen, Alexander Erich Eugen Senning

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Three new alfa-oxo thione S-(tert-alkylimides) 3 have been prepared. Thiocarbonyl S- (tert-alkylimides) react with chlorine and bromine, but not with other halogens or pseudohalogens, to give the corresponding dihalomethylene compounds. The pyrolysis of 3 leads to the corresponding 1,2,4-trithiolanes, presumably via intermediate thiosulfines. Ozonization of 3 gives the corresponding alfa-diketones.
    Original languageEnglish
    JournalSulfur Letters
    Volume22
    Issue number2
    Pages (from-to)73-84
    Publication statusPublished - 1999

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