In this letter, an all-optical incoherent scheme for generation of binary phase-coded ultra-wideband (UWB) impulse radio signals is proposed. The generated UWB pulses utilize relaxation oscillations of an optically injected distributed feedback laser that are binary phase encoded (0 and ) and meet the requirements of Federal Communications Commission regulations. We experimentally demonstrated a 781.25-Mb/s UWB-over-fiber transmission system. A digital-signal-processing-based receiver is employed to calculate the bit-error rate. Our proposed system has potential application in future high-speed UWB impulse radio over optical fiber access networks.