Excess Enthalpies in Binary Systems of Isomeric C8 Aliphatic Monoethers with Acetonitrile and Their Description by the COSMO-SAC Model

Lukasz Ruszczynski, Mateusz Reda, Marek Krolikowski, Marek Glinski, Tadeusz Hofman

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The excess enthalpies at 298.15 and 308.15 K for six binary mixtures of acetonitrile + C8 aliphatic ether {heptylmethyl ether CH3OnC7H15, or ethylhexyl ether C2H5OnC6H13,or pentyl propyl ether nC3H7OnC5H11, or isopentyl propyl ether nC3H7OiC5H11, or dibutyl ether nC4H9OnC4H9, or butyl isobutylether nC4H9OiC4H9} have been determined by isothermal titration calorimetry using the TA Instruments (model TAM III) calorimeter. The possibility of the COSMO-SAC model to account for the thermodynamic differences between these systems has been tested.
Original languageEnglish
JournalJournal of Chemical and Engineering Data
Volume61
Pages (from-to)996−1002
ISSN0021-9568
DOIs
Publication statusPublished - 2016
Externally publishedYes

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Non-DTU publication

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