Abstract
The excess enthalpies at 298.15 and 308.15 K for six binary mixtures of acetonitrile + C8 aliphatic ether {heptylmethyl ether CH3OnC7H15, or ethylhexyl ether C2H5OnC6H13,or pentyl propyl ether nC3H7OnC5H11, or isopentyl propyl ether nC3H7OiC5H11, or dibutyl ether nC4H9OnC4H9, or butyl isobutylether nC4H9OiC4H9} have been determined by isothermal titration calorimetry using the TA Instruments (model TAM III) calorimeter. The possibility of the COSMO-SAC model to account for the thermodynamic differences between these systems has been tested.
Original language | English |
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Journal | Journal of Chemical and Engineering Data |
Volume | 61 |
Pages (from-to) | 996−1002 |
ISSN | 0021-9568 |
DOIs | |
Publication status | Published - 2016 |
Externally published | Yes |