Abstract
| Original language | English |
|---|---|
| Journal | Journal of Power Sources |
| Volume | 360 |
| Pages (from-to) | 520-527 |
| ISSN | 0378-7753 |
| DOIs | |
| Publication status | Published - 2017 |
Keywords
- Ex-situ
- Ptychography
- Nano-tomography
- Solid oxide cell
- Oxidation
- Reduction
Cite this
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Ex-situ tracking solid oxide cell electrode microstructural evolution in a redox cycle by high resolution ptychographic nanotomography. / De Angelis, Salvatore; Jørgensen, Peter Stanley; Esposito, Vincenzo; Hsiao Rho Tsai, Esther ; Holler, Mirko; Kreka, Kosova; Abdellahi, Ebtisam; Bowen, Jacob R.
In: Journal of Power Sources, Vol. 360, 2017, p. 520-527.Research output: Contribution to journal › Journal article › Research › peer-review
TY - JOUR
T1 - Ex-situ tracking solid oxide cell electrode microstructural evolution in a redox cycle by high resolution ptychographic nanotomography
AU - De Angelis, Salvatore
AU - Jørgensen, Peter Stanley
AU - Esposito, Vincenzo
AU - Hsiao Rho Tsai, Esther
AU - Holler, Mirko
AU - Kreka, Kosova
AU - Abdellahi, Ebtisam
AU - Bowen, Jacob R.
PY - 2017
Y1 - 2017
N2 - For solid oxide fuel and electrolysis cells, precise tracking of 3D microstructural change in the electrodes during operation is considered critical to understand the complex relationship between electrode microstructure and performance. Here, for the first time, we report a significant step towards this aim by visualizing a complete redox cycle in a solid oxide cell (SOC) electrode. The experiment demonstrates synchrotron-based ptychography as a method of imaging SOC electrodes, providing an unprecedented combination of 3D image quality and spatial resolution among non-destructive imaging techniques. Spatially registered 3D reconstructions of the same location in the electrode clearly show the evolution of the microstructure from the pristine state to the oxidized state and to the reduced state. A complete mechanical destruction of the zirconia backbone is observed via grain boundary fracture, the nickel and pore networks undergo major reorganization and the formation of internal voids is observed in the nickel-oxide particles after the oxidation. These observations are discussed in terms of reaction kinetics, electrode mechanical stress and the consequences of redox cycling on electrode performance.
AB - For solid oxide fuel and electrolysis cells, precise tracking of 3D microstructural change in the electrodes during operation is considered critical to understand the complex relationship between electrode microstructure and performance. Here, for the first time, we report a significant step towards this aim by visualizing a complete redox cycle in a solid oxide cell (SOC) electrode. The experiment demonstrates synchrotron-based ptychography as a method of imaging SOC electrodes, providing an unprecedented combination of 3D image quality and spatial resolution among non-destructive imaging techniques. Spatially registered 3D reconstructions of the same location in the electrode clearly show the evolution of the microstructure from the pristine state to the oxidized state and to the reduced state. A complete mechanical destruction of the zirconia backbone is observed via grain boundary fracture, the nickel and pore networks undergo major reorganization and the formation of internal voids is observed in the nickel-oxide particles after the oxidation. These observations are discussed in terms of reaction kinetics, electrode mechanical stress and the consequences of redox cycling on electrode performance.
KW - Ex-situ
KW - Ptychography
KW - Nano-tomography
KW - Solid oxide cell
KW - Oxidation
KW - Reduction
U2 - 10.1016/j.jpowsour.2017.06.035
DO - 10.1016/j.jpowsour.2017.06.035
M3 - Journal article
VL - 360
SP - 520
EP - 527
JO - Journal of Power Sources
JF - Journal of Power Sources
SN - 0378-7753
ER -