Evaluation of LSF based SOFC Cathodes using Cone-shaped Electrodes

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    Abstract

    Seven La1-xSrxFeO3-delta (x = 0, 0.05, 0.15, 0.25, 0.35, 0.50, 0.70) based perovskites were synthesized using the glycine-nitrate method. The La1-xSrxFeO3-delta compounds were characterized with powder X-ray diffraction and electrochemical impedance spectroscopy on cone-shaped electrodes using a Ce1.9Gd0.1O1.95 electrolyte. The activity of the La1-xSrxFeO3-delta based perovskites towards the electrochemical reduction of oxygen was strongly dependent of the strontium content, the activity being highest for the composition La0.85Sr0.15FeO3-delta. The results indicates that Fe(III) is the catalytic active specie towards the electrochemical reduction of oxygen in a solid oxide fuel cell on La1-xSrxFeO3-delta compounds. The results also show that oxide ion vacancies in the perovskite structure are important for the electrochemical reduction of oxygen. However, the effect of ordering of oxide ion vacancies for the strontium rich compounds can not be excluded.
    Original languageEnglish
    JournalECS Transactions
    Volume13
    Issue number26
    Pages (from-to)153-160
    ISSN1938-5862
    DOIs
    Publication statusPublished - 2008
    Event213th ECS Meeting: B6 - Ionic and Mixed Conducting Ceramics 6 - Phoenix Convention Center, Phoenix, AZ, United States
    Duration: 18 May 200823 May 2008
    Conference number: 213th
    http://www.electrochem.org/meetings/biannual/213/213.htm

    Conference

    Conference213th ECS Meeting
    Number213th
    LocationPhoenix Convention Center
    CountryUnited States
    CityPhoenix, AZ
    Period18/05/200823/05/2008
    Internet address

    Bibliographical note

    Copyright The Electrochemical Society, Inc. [2008]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

    Cite this

    @inproceedings{a621d5cd130249c2be2c57ffdf9e80d5,
    title = "Evaluation of LSF based SOFC Cathodes using Cone-shaped Electrodes",
    abstract = "Seven La1-xSrxFeO3-delta (x = 0, 0.05, 0.15, 0.25, 0.35, 0.50, 0.70) based perovskites were synthesized using the glycine-nitrate method. The La1-xSrxFeO3-delta compounds were characterized with powder X-ray diffraction and electrochemical impedance spectroscopy on cone-shaped electrodes using a Ce1.9Gd0.1O1.95 electrolyte. The activity of the La1-xSrxFeO3-delta based perovskites towards the electrochemical reduction of oxygen was strongly dependent of the strontium content, the activity being highest for the composition La0.85Sr0.15FeO3-delta. The results indicates that Fe(III) is the catalytic active specie towards the electrochemical reduction of oxygen in a solid oxide fuel cell on La1-xSrxFeO3-delta compounds. The results also show that oxide ion vacancies in the perovskite structure are important for the electrochemical reduction of oxygen. However, the effect of ordering of oxide ion vacancies for the strontium rich compounds can not be excluded.",
    keywords = "Br{\ae}ndselsceller og brint",
    author = "{Kammer Hansen}, Kent and Mogensen, {Mogens Bjerg}",
    note = "Copyright The Electrochemical Society, Inc. [2008]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).",
    year = "2008",
    doi = "10.1149/1.3050387",
    language = "English",
    volume = "13",
    pages = "153--160",
    journal = "E C S Transactions",
    issn = "1938-5862",
    publisher = "The Electrochemical Society",
    number = "26",

    }

    Evaluation of LSF based SOFC Cathodes using Cone-shaped Electrodes. / Kammer Hansen, Kent; Mogensen, Mogens Bjerg.

    In: ECS Transactions, Vol. 13, No. 26, 2008, p. 153-160.

    Research output: Contribution to journalConference articleResearchpeer-review

    TY - GEN

    T1 - Evaluation of LSF based SOFC Cathodes using Cone-shaped Electrodes

    AU - Kammer Hansen, Kent

    AU - Mogensen, Mogens Bjerg

    N1 - Copyright The Electrochemical Society, Inc. [2008]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

    PY - 2008

    Y1 - 2008

    N2 - Seven La1-xSrxFeO3-delta (x = 0, 0.05, 0.15, 0.25, 0.35, 0.50, 0.70) based perovskites were synthesized using the glycine-nitrate method. The La1-xSrxFeO3-delta compounds were characterized with powder X-ray diffraction and electrochemical impedance spectroscopy on cone-shaped electrodes using a Ce1.9Gd0.1O1.95 electrolyte. The activity of the La1-xSrxFeO3-delta based perovskites towards the electrochemical reduction of oxygen was strongly dependent of the strontium content, the activity being highest for the composition La0.85Sr0.15FeO3-delta. The results indicates that Fe(III) is the catalytic active specie towards the electrochemical reduction of oxygen in a solid oxide fuel cell on La1-xSrxFeO3-delta compounds. The results also show that oxide ion vacancies in the perovskite structure are important for the electrochemical reduction of oxygen. However, the effect of ordering of oxide ion vacancies for the strontium rich compounds can not be excluded.

    AB - Seven La1-xSrxFeO3-delta (x = 0, 0.05, 0.15, 0.25, 0.35, 0.50, 0.70) based perovskites were synthesized using the glycine-nitrate method. The La1-xSrxFeO3-delta compounds were characterized with powder X-ray diffraction and electrochemical impedance spectroscopy on cone-shaped electrodes using a Ce1.9Gd0.1O1.95 electrolyte. The activity of the La1-xSrxFeO3-delta based perovskites towards the electrochemical reduction of oxygen was strongly dependent of the strontium content, the activity being highest for the composition La0.85Sr0.15FeO3-delta. The results indicates that Fe(III) is the catalytic active specie towards the electrochemical reduction of oxygen in a solid oxide fuel cell on La1-xSrxFeO3-delta compounds. The results also show that oxide ion vacancies in the perovskite structure are important for the electrochemical reduction of oxygen. However, the effect of ordering of oxide ion vacancies for the strontium rich compounds can not be excluded.

    KW - Brændselsceller og brint

    U2 - 10.1149/1.3050387

    DO - 10.1149/1.3050387

    M3 - Conference article

    VL - 13

    SP - 153

    EP - 160

    JO - E C S Transactions

    JF - E C S Transactions

    SN - 1938-5862

    IS - 26

    ER -