Estimating trichloroethylene, 1,1,1-trichloroethane, and atrazine dehalogenation reactivity of bimetallic nickel/iron nanoparticles by simple colorimetric assay by way of 4-chlorophenol reduction

Paul D. Mines, Kamilla Marie Speht Kaarsholm, Ariadni Droumpali, Henrik Rasmus Andersen, Yuhoon Hwang*

*Corresponding author for this work

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Abstract

A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.
Original languageEnglish
JournalEnvironmental Engineering Research
Volume25
Issue number2
Pages (from-to)197-204
ISSN1226-1025
DOIs
Publication statusPublished - 2020

Bibliographical note

This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0/) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Keywords

  • Colorimetric assay
  • Dehalogenation
  • Nanoscale zero-valent iron
  • Trichloroethylene
  • 4-chlorophenol

Cite this

@article{8077fc90ebd5449db8175ad2a09e5118,
title = "Estimating trichloroethylene, 1,1,1-trichloroethane, and atrazine dehalogenation reactivity of bimetallic nickel/iron nanoparticles by simple colorimetric assay by way of 4-chlorophenol reduction",
abstract = "A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.",
keywords = "Colorimetric assay, Dehalogenation, Nanoscale zero-valent iron, Trichloroethylene, 4-chlorophenol",
author = "Mines, {Paul D.} and Kaarsholm, {Kamilla Marie Speht} and Ariadni Droumpali and Andersen, {Henrik Rasmus} and Yuhoon Hwang",
note = "This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.",
year = "2020",
doi = "10.4491/eer.2019.016",
language = "English",
volume = "25",
pages = "197--204",
journal = "Environmental Engineering Research",
issn = "1226-1025",
publisher = "Korean Society of Environmental Engineers",
number = "2",

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TY - JOUR

T1 - Estimating trichloroethylene, 1,1,1-trichloroethane, and atrazine dehalogenation reactivity of bimetallic nickel/iron nanoparticles by simple colorimetric assay by way of 4-chlorophenol reduction

AU - Mines, Paul D.

AU - Kaarsholm, Kamilla Marie Speht

AU - Droumpali, Ariadni

AU - Andersen, Henrik Rasmus

AU - Hwang, Yuhoon

N1 - This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/3.0/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

PY - 2020

Y1 - 2020

N2 - A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.

AB - A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.

KW - Colorimetric assay

KW - Dehalogenation

KW - Nanoscale zero-valent iron

KW - Trichloroethylene

KW - 4-chlorophenol

U2 - 10.4491/eer.2019.016

DO - 10.4491/eer.2019.016

M3 - Journal article

VL - 25

SP - 197

EP - 204

JO - Environmental Engineering Research

JF - Environmental Engineering Research

SN - 1226-1025

IS - 2

ER -