Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

Jerrik Jørgen Mielby; Søren Kegnæs

doi:10.1007/s10562-013-1088-1

Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

Jerrik Jørgen Mielby, Søren Kegnæs

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome challenges with catalyst separation and reuse.

Original language	English
Journal	Catalysis Letters
Volume	143
Issue number	11
Pages (from-to)	1162-1165
ISSN	1011-372X
DOIs	https://doi.org/10.1007/s10562-013-1088-1
Publication status	Published - 2013

Keywords

Green chemistry
Epoxidation
Alkenes
Oxidation
Liquid-phase oxidation

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10.1007/s10562-013-1088-1

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abstract = "A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome challenges with catalyst separation and reuse.",

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AU - Mielby, Jerrik Jørgen

AU - Kegnæs, Søren

PY - 2013

Y1 - 2013

N2 - A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome challenges with catalyst separation and reuse.

AB - A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome challenges with catalyst separation and reuse.

KW - Green chemistry

KW - Epoxidation

KW - Alkenes

KW - Oxidation

KW - Liquid-phase oxidation

U2 - 10.1007/s10562-013-1088-1

DO - 10.1007/s10562-013-1088-1

M3 - Journal article

SN - 1011-372X

VL - 143

SP - 1162

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JO - Catalysis Letters

JF - Catalysis Letters

IS - 11

ER -

Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

Abstract

Keywords

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