Enzymatically mediated incorporation of 2-chlorophenol 4-chlorophenol into humic acids

P. Lassen; A. Randall; O. Jørgensen; P. Warwick; L. Carlsen

doi:10.1016/0045-6535(94)90221-6

Enzymatically mediated incorporation of 2-chlorophenol 4-chlorophenol into humic acids

P. Lassen, A. Randall, O. Jørgensen, P. Warwick, L. Carlsen

Research output: Contribution to journal › Journal article › Research

Abstract

A possible route to chlorinated humic substances in the environment, is an indirect chlorination of humic material by enzymatically mediated incorporation of low molecular weight organo-chlorine compounds into the humic skeleton. The enzymatically mediated incorporation of 2-chlorophenol and 4-chlorophenol into humic acids by Horseradish Peroxidase is reported. The incorporation is accompanied by a significant polymerization of the chlorophenols. The stability of the chlorinated humic acids as well as the environmental implication are discussed.

Original language	English
Journal	Chemosphere
Volume	28
Issue number	4
Pages (from-to)	703-710
ISSN	0045-6535
DOIs	https://doi.org/10.1016/0045-6535(94)90221-6
Publication status	Published - 1994

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title = "Enzymatically mediated incorporation of 2-chlorophenol 4-chlorophenol into humic acids",

abstract = "A possible route to chlorinated humic substances in the environment, is an indirect chlorination of humic material by enzymatically mediated incorporation of low molecular weight organo-chlorine compounds into the humic skeleton. The enzymatically mediated incorporation of 2-chlorophenol and 4-chlorophenol into humic acids by Horseradish Peroxidase is reported. The incorporation is accompanied by a significant polymerization of the chlorophenols. The stability of the chlorinated humic acids as well as the environmental implication are discussed. ",

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AU - Lassen, P.

AU - Randall, A.

AU - Jørgensen, O.

AU - Warwick, P.

AU - Carlsen, L.

PY - 1994

Y1 - 1994

N2 - A possible route to chlorinated humic substances in the environment, is an indirect chlorination of humic material by enzymatically mediated incorporation of low molecular weight organo-chlorine compounds into the humic skeleton. The enzymatically mediated incorporation of 2-chlorophenol and 4-chlorophenol into humic acids by Horseradish Peroxidase is reported. The incorporation is accompanied by a significant polymerization of the chlorophenols. The stability of the chlorinated humic acids as well as the environmental implication are discussed.

AB - A possible route to chlorinated humic substances in the environment, is an indirect chlorination of humic material by enzymatically mediated incorporation of low molecular weight organo-chlorine compounds into the humic skeleton. The enzymatically mediated incorporation of 2-chlorophenol and 4-chlorophenol into humic acids by Horseradish Peroxidase is reported. The incorporation is accompanied by a significant polymerization of the chlorophenols. The stability of the chlorinated humic acids as well as the environmental implication are discussed.

KW - Miljøaspekter ved energi- og industriproduktion

U2 - 10.1016/0045-6535(94)90221-6

DO - 10.1016/0045-6535(94)90221-6

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VL - 28

SP - 703

EP - 710

JO - Chemosphere

JF - Chemosphere

IS - 4

ER -

Enzymatically mediated incorporation of 2-chlorophenol 4-chlorophenol into humic acids

Abstract

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