Enhanced thermal and electrochemical properties in La_0.8Sr_0.2MnO_3-δ-Pr₆O₁₁ nanocomposite cathodes for solid oxide fuel cells

La_0.8Sr_0.2MnO_3-δ (LSM)-Pr₆O₁₁ nanocomposite electrodes are prepared via a one-step spray-pyrolysis deposition directly onto the electrolyte and evaluated as cathodes for solid oxide fuel cells (SOFCs). The nanoscale integration of two immiscible phases effectively inhibits grain growth while improving mechanical compatibility with the electrolyte. The confinement of the fluorite Pr₆O₁₁ phase at the nanoscale during the self-assembly process, achieved by adding the perovskite-type LSM phase with a different crystal structure, hinder the thermally induced phase transitions of Pr₆O₁₁ compared to the bulk material. The extended triple-phase-boundary (TPB) in these nanoengineered electrodes leads to exceptional electrochemical performance, achieving a polarization resistance of 0.21 Ω cm² at 650 °C, significantly lower than the 5.8 Ω cm² measured for a traditional screen-printed LSM cathode. An anode-supported cell incorporating these nanocomposite electrodes achieves a peak power density of 1.22 W cm⁻² at 800 °C in wet H₂, far exceeding the 0.58 W cm⁻² observed for the single cell with a commercial LSM electrode under identical conditions. These findings underscore the significant benefits of advanced nanostructured electrode designs and innovative fabrication techniques in achieving high performance and durability in SOFCs.