Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes

Jonas Himmelstrup, Mikkel Burggraaf Buendia, Xing-Wen Sun, Søren Kramer*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp2)-C(sp2) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.
Original languageEnglish
JournalChemical Communications
Volume55
Issue number86
Pages (from-to)12988-12991
Number of pages4
ISSN1359-7345
DOIs
Publication statusPublished - 2019

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