Elucidation of the Oxygen Reduction Volcano in Alkaline Media using a Copper-Platinum(111) Alloy

Kim Degn Jensen, Jakub Tymoczko, Jan Rossmeisl, Aliaksandr S. Bandarenka, Ib Chorkendorff, Maria Escudero Escribano, Ifan E. L. Stephens*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

The relationship between the binding of the reaction intermediates and oxygen reduction activity in alkaline media was experimentally explored. By introducing Cu into the 2nd surface layer of a Pt(111) single crystal, the surface reactivity was tuned. In both 0.1(M) NaOH and 0.1(M) KOH, the optimal catalyst should exhibit OH binding circa 0.1 eV weaker than Pt(111), via a Sabatier volcano; this observation suggests that the reaction is mediated via the same surface bound intermediates as in acid, in contrast to previous reports. In 0.1(M) KOH, the alloy catalyst at the peak of the volcano exhibits a maximum activity of 10 ± 8 mAcm2 at 0.9 V vs. a reversible hydrogen electrode (RHE). This activity constitutes a circa 60-fold increase over Pt(111) in 0.1(M) HClO4.
Original languageEnglish
JournalAngewandte chemie-international edition
Volume57
Issue number11
Pages (from-to)2800-2805
ISSN1433-7851
DOIs
Publication statusPublished - 2018

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