Electrolyte gate controlled metal-insulator transitions of the CaZrO3/SrTiO3 heterointerface

Wei Niu, Yongda Chen, Yulin Gan, Yu Zhang, Xiaoqian Zhang, Xiao Yuan, Zhi Cao, Wenqing Liu, Yongbing Xu, Rong Zhang, Nini Pryds, Yunzhong Chen, Yong Pu, Xuefeng Wang*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Two-dimensional electron gas (2DEG) at a complex oxide interface shows an extraordinary spectrum of intriguing phenomena and functionality. Another oxide 2DEG was recently created via strain-induced polarization at an otherwise nonpolar perovskite-type interface of CaZrO3/SrTiO3 (CZO/STO). Herein, we report an effective way to tune the CZO/STO interface via ionic liquid (IL) electrolyte gating. An unexpected metal-insulator transition of the interfacial 2DEG occurs readily with the immersion of the sample in an IL even before the gate voltage is applied. This suggests the presence of intrinsic polarization of CZO, which could act as a negative bias. The carrier density is found to be suppressed and shows a temperature-independent behavior after electrolyte gating which also resulted in higher electron mobility. These results suggest that the oxygen vacancies are annihilated via oxygen electromigration to the interface induced by electrolyte gating. The effective tunability by IL gating shed more light on the mechanism of electrolyte gating on the buried heterointerface.
Original languageEnglish
Article number061601
JournalApplied Physics Letters
Volume115
Issue number6
Number of pages5
ISSN0003-6951
DOIs
Publication statusPublished - 2019

Cite this

Niu, W., Chen, Y., Gan, Y., Zhang, Y., Zhang, X., Yuan, X., Cao, Z., Liu, W., Xu, Y., Zhang, R., Pryds, N., Chen, Y., Pu, Y., & Wang, X. (2019). Electrolyte gate controlled metal-insulator transitions of the CaZrO3/SrTiO3 heterointerface. Applied Physics Letters, 115(6), [061601]. https://doi.org/10.1063/1.5108813