Electroless Growth of Aluminum Dendrites in NaCl-AlCl3 Melts.

Qingfeng Li; H.A. Hjuler; Rolf W. Berg; Niels Bjerrum

doi:10.1149/1.2096377

Electroless Growth of Aluminum Dendrites in NaCl-AlCl3 Melts.

Qingfeng Li, H.A. Hjuler, Rolf W. Berg, Niels Bjerrum

Department of Chemistry

Technical University of Denmark

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Abstract

The spontaneous growth of aluminum dendrites after deposition was observed and examined in sodium chloride-aluminumchloride melts. The concentration gradient of AlCl3 in the vicinity of the cathode surface resulting from electrolysisconstitutes a type of concentration cell with aluminum dendrites as electrodes. The short-circuit discharge of thecell is found to be the driving force for the growth of aluminum dendrites. Such a concentration gradient is proposed to beone of the causes for dendrite formation in the case of metal deposition.

Original language	English
Journal	Journal of The Electrochemical Society
Volume	136
Issue number	10
Pages (from-to)	2940-2943
ISSN	0013-4651
DOIs	https://doi.org/10.1149/1.2096377
Publication status	Published - 1989

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Copyright The Electrochemical Society, Inc. [1989]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

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title = "Electroless Growth of Aluminum Dendrites in NaCl-AlCl3 Melts.",

abstract = "The spontaneous growth of aluminum dendrites after deposition was observed and examined in sodium chloride-aluminumchloride melts. The concentration gradient of AlCl3 in the vicinity of the cathode surface resulting from electrolysisconstitutes a type of concentration cell with aluminum dendrites as electrodes. The short-circuit discharge of thecell is found to be the driving force for the growth of aluminum dendrites. Such a concentration gradient is proposed to beone of the causes for dendrite formation in the case of metal deposition.",

author = "Qingfeng Li and H.A. Hjuler and Berg, {Rolf W.} and Niels Bjerrum",

note = "Copyright The Electrochemical Society, Inc. [1989]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).",

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AU - Li, Qingfeng

AU - Hjuler, H.A.

AU - Berg, Rolf W.

AU - Bjerrum, Niels

N1 - Copyright The Electrochemical Society, Inc. [1989]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

PY - 1989

Y1 - 1989

N2 - The spontaneous growth of aluminum dendrites after deposition was observed and examined in sodium chloride-aluminumchloride melts. The concentration gradient of AlCl3 in the vicinity of the cathode surface resulting from electrolysisconstitutes a type of concentration cell with aluminum dendrites as electrodes. The short-circuit discharge of thecell is found to be the driving force for the growth of aluminum dendrites. Such a concentration gradient is proposed to beone of the causes for dendrite formation in the case of metal deposition.

AB - The spontaneous growth of aluminum dendrites after deposition was observed and examined in sodium chloride-aluminumchloride melts. The concentration gradient of AlCl3 in the vicinity of the cathode surface resulting from electrolysisconstitutes a type of concentration cell with aluminum dendrites as electrodes. The short-circuit discharge of thecell is found to be the driving force for the growth of aluminum dendrites. Such a concentration gradient is proposed to beone of the causes for dendrite formation in the case of metal deposition.

U2 - 10.1149/1.2096377

DO - 10.1149/1.2096377

M3 - Journal article

SN - 0013-4651

VL - 136

SP - 2940

EP - 2943

JO - Journal of The Electrochemical Society

JF - Journal of The Electrochemical Society

IS - 10

ER -

Electroless Growth of Aluminum Dendrites in NaCl-AlCl3 Melts.

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