Electrochemical removal of salts from masonry - Experiences from pilot scale

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    Abstract

    A pilot experiment with newly developed electrodes was tested for removal of contaminating salts from brick masonry where plaster peeling was a problem. A high concentration of sulfate was found at the height where the paint peeling was most pronounced. The concentrations of chloride and nitrate were smaller, though in dangerous concentrations at some points. In the applied electric field, chloride and nitrate were efficiently removed. Sulfate, on the other hand, was less mobile, due to lower solubility of sulphate salts and thus lower percentage in ionic form and mobile for electromigration. The mean concentration of sulfate was decreased from 0.68 wt% to 0.46 wt% during the approx. 4 months of treatment. The removal rate for sulphate did not decrease significantly during the treatment period and it is expected that reduction in sulphate concentration could continue over longer duration. The electrode units worked perfect and efficiently prevented the acid produced at the anode from reaching the masonry. The contaminating ions from the masonry concentrated inside the electrodes and were removed from the site with the electrodes.
    Original languageEnglish
    Title of host publicationSalt Weathering on Buildings and Stone Sculptures : Proceedings from the international conference
    Number of pages392
    PublisherDTU Byg, Danmarks Tekniske Universitet
    Publication date2008
    Pages341-250
    ISBN (Print)9788778772732
    Publication statusPublished - 2008
    Event1st International Conference on Salt Weathering on Buildings and Stone Sculptures - The National Museum, Copenhagen, Denmark
    Duration: 22 Oct 200824 Oct 2008
    Conference number: 1

    Conference

    Conference1st International Conference on Salt Weathering on Buildings and Stone Sculptures
    Number1
    LocationThe National Museum
    Country/TerritoryDenmark
    CityCopenhagen
    Period22/10/200824/10/2008

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