Electrical conductivity of Ni–YSZ composites: Degradation due to Ni particle growth

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    Abstract

    The short-term changes in the electrical conductivity of Ni–YSZ composites (cermets) suitable for use in Solid Oxide Fuel Cells (SOFC) were measured by an in-situ 4-point DC technique. The isothermal reduction was carried out in dry, humidified or wet hydrogen at temperatures from 600 to 1000°C. While the cermets reduced at 600°C showed a stable conductivity of 1000–1200S/cm, rapid initial conductivity loss was observed at elevated temperatures. At 1000°C the conductivity degraded nearly instantaneously to about 800S/cm, and continued to decline fast to about 400S/cm. At 850°C, the presence of steam did have an accelerating effect on the conductivity loss. Scanning Electron Microscopy of cermets reduced in different conditions showed increasing particle size and loss of metal-to-metal percolation in the samples reduced at higher temperatures. The short-term changes in conductivity were modelled using two different semi-empirical approaches. Thermodynamic calculations were carried out to assess the vaporisation of Ni in the conditions tested. The rate and mechanisms of conductivity degradation due to Ni particle growth are discussed in light of the measurements, modelling and literature data.
    Original languageEnglish
    JournalSolid State Ionics
    Volume189
    Issue number1
    Pages (from-to)82-90
    ISSN0167-2738
    DOIs
    Publication statusPublished - 2011

    Keywords

    • Solid Oxide Fuel Cells

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