Efficient transformation of CO2 to cyclic carbonates using bifunctional protic ionic liquids under mild conditions

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A series of 1,8-diazabicyclo-[5.4.0]undec-7-ene (DBU) based bifunctional protic ionic liquids (DBPILs) were easily prepared by acid–base reactions at room temperature. They were used to catalyze the cycloaddition reaction of CO2 with epoxides under mild conditions. As a metal free catalyst, the best DBPIL showed a 92% yield of products within 6 hours at 30 °C and 1 bar CO2 without any solvents and co-catalysts. It could afford carbonates in good yields with broad epoxide substrate scope and CO2 from simulated flue gas (15% CO2/85% N2). IR spectroscopy and DFT studies were carried out to investigate the mechanism of the cycloaddition reaction. The results showed that the DBPILs could activate both CO2 and epoxides by alkoxy anions and powerful hydrogen-bonding, which was well consistent with experiments.
Original languageEnglish
JournalGreen Chemistry
Volume21
Issue number12
Pages (from-to)3456-3463
ISSN1463-9262
DOIs
Publication statusPublished - 2019
CitationsWeb of Science® Times Cited: No match on DOI

ID: 183758472