Effect of Support in Heterogeneous Ruthenium Catalysts Used for the Selective Aerobic Oxidation of HMF in Water

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Heterogeneous ruthenium-based catalysts were applied in the selective, aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, to form 2,5-furandicarboxylic acid. The oxidation reactions were performed in water with dioxygen as the oxidant at different pressures without added base. Catalysts were prepared by depositing catalytically active Ru(OH)x species on a number of different supports, such as titanium-, aluminum-, cerium-, zirconium-, magnesium- and lanthanum oxides, magnetite, spinel, hydrotalcite and hydroxyapatite. All the catalysts were found to be active in the oxidation reactions, and the choice of support was demonstrated to be important for the catalytic performance.
Original languageEnglish
JournalTopics in Catalysis
Volume54
Issue number16-18
Pages (from-to)1318-1324
ISSN1022-5528
DOIs
Publication statusPublished - 2011

Keywords

  • Supported catalysts
  • 5-hydroxymethylfurfural
  • 2,5-furandicarboxylic acid
  • Oxidation
  • Ruthenium

Cite this

@article{1710a33929954b85bda17d6864e470a0,
title = "Effect of Support in Heterogeneous Ruthenium Catalysts Used for the Selective Aerobic Oxidation of HMF in Water",
abstract = "Heterogeneous ruthenium-based catalysts were applied in the selective, aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, to form 2,5-furandicarboxylic acid. The oxidation reactions were performed in water with dioxygen as the oxidant at different pressures without added base. Catalysts were prepared by depositing catalytically active Ru(OH)x species on a number of different supports, such as titanium-, aluminum-, cerium-, zirconium-, magnesium- and lanthanum oxides, magnetite, spinel, hydrotalcite and hydroxyapatite. All the catalysts were found to be active in the oxidation reactions, and the choice of support was demonstrated to be important for the catalytic performance.",
keywords = "Supported catalysts, 5-hydroxymethylfurfural, 2,5-furandicarboxylic acid, Oxidation, Ruthenium",
author = "Yury Gorbanev and S{\o}ren Kegn{\ae}s and Anders Riisager",
year = "2011",
doi = "10.1007/s11244-011-9754-2",
language = "English",
volume = "54",
pages = "1318--1324",
journal = "Topics in Catalysis",
issn = "1022-5528",
publisher = "Springer New York",
number = "16-18",

}

Effect of Support in Heterogeneous Ruthenium Catalysts Used for the Selective Aerobic Oxidation of HMF in Water. / Gorbanev, Yury; Kegnæs, Søren; Riisager, Anders.

In: Topics in Catalysis, Vol. 54, No. 16-18, 2011, p. 1318-1324.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Effect of Support in Heterogeneous Ruthenium Catalysts Used for the Selective Aerobic Oxidation of HMF in Water

AU - Gorbanev, Yury

AU - Kegnæs, Søren

AU - Riisager, Anders

PY - 2011

Y1 - 2011

N2 - Heterogeneous ruthenium-based catalysts were applied in the selective, aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, to form 2,5-furandicarboxylic acid. The oxidation reactions were performed in water with dioxygen as the oxidant at different pressures without added base. Catalysts were prepared by depositing catalytically active Ru(OH)x species on a number of different supports, such as titanium-, aluminum-, cerium-, zirconium-, magnesium- and lanthanum oxides, magnetite, spinel, hydrotalcite and hydroxyapatite. All the catalysts were found to be active in the oxidation reactions, and the choice of support was demonstrated to be important for the catalytic performance.

AB - Heterogeneous ruthenium-based catalysts were applied in the selective, aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, to form 2,5-furandicarboxylic acid. The oxidation reactions were performed in water with dioxygen as the oxidant at different pressures without added base. Catalysts were prepared by depositing catalytically active Ru(OH)x species on a number of different supports, such as titanium-, aluminum-, cerium-, zirconium-, magnesium- and lanthanum oxides, magnetite, spinel, hydrotalcite and hydroxyapatite. All the catalysts were found to be active in the oxidation reactions, and the choice of support was demonstrated to be important for the catalytic performance.

KW - Supported catalysts

KW - 5-hydroxymethylfurfural

KW - 2,5-furandicarboxylic acid

KW - Oxidation

KW - Ruthenium

U2 - 10.1007/s11244-011-9754-2

DO - 10.1007/s11244-011-9754-2

M3 - Journal article

VL - 54

SP - 1318

EP - 1324

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

IS - 16-18

ER -