Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties

Ahsanul Kabir*, Simone Santucci, Ngo Van Nong, Maxim Varenik, Igor Lubomirsky, Robin Nigon, Paul Muralt, Vincenzo Esposito

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VÖ) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.
Original languageEnglish
JournalActa Materialia
Volume174
Pages (from-to)53-60
ISSN1359-6454
DOIs
Publication statusPublished - 2019

Keywords

  • Electrostriction
  • Vacancies
  • Gadolinium-doped ceria
  • Sintering

Cite this

Kabir, Ahsanul ; Santucci, Simone ; Van Nong, Ngo ; Varenik, Maxim ; Lubomirsky, Igor ; Nigon, Robin ; Muralt, Paul ; Esposito, Vincenzo. / Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties. In: Acta Materialia. 2019 ; Vol. 174. pp. 53-60.
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abstract = "Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (V{\"O}) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.",
keywords = "Electrostriction, Vacancies, Gadolinium-doped ceria, Sintering",
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Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties. / Kabir, Ahsanul; Santucci, Simone; Van Nong, Ngo; Varenik, Maxim ; Lubomirsky, Igor; Nigon, Robin ; Muralt, Paul ; Esposito, Vincenzo.

In: Acta Materialia, Vol. 174, 2019, p. 53-60.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties

AU - Kabir, Ahsanul

AU - Santucci, Simone

AU - Van Nong, Ngo

AU - Varenik, Maxim

AU - Lubomirsky, Igor

AU - Nigon, Robin

AU - Muralt, Paul

AU - Esposito, Vincenzo

PY - 2019

Y1 - 2019

N2 - Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VÖ) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.

AB - Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (VÖ) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce0.9Gd0.1O2-δ, δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.

KW - Electrostriction

KW - Vacancies

KW - Gadolinium-doped ceria

KW - Sintering

U2 - 10.1016/j.actamat.2019.05.009

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