Abstract
| Original language | English |
|---|---|
| Journal | Journal of Chemical Physics |
| Volume | 104 |
| Issue number | 9 |
| Pages (from-to) | 3234-3243 |
| ISSN | 0021-9606 |
| DOIs | |
| Publication status | Published - 1996 |
Bibliographical note
Copyright (1996) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.Keywords
- FORMULATION
- TRANSITIONS
Cite this
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Dynamic aspects of electronic predissociation. / Grønager, Michael; Henriksen, Niels Engholm.
In: Journal of Chemical Physics, Vol. 104, No. 9, 1996, p. 3234-3243.Research output: Contribution to journal › Journal article › Research › peer-review
TY - JOUR
T1 - Dynamic aspects of electronic predissociation
AU - Grønager, Michael
AU - Henriksen, Niels Engholm
N1 - Copyright (1996) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.
PY - 1996
Y1 - 1996
N2 - We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.
AB - We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.
KW - FORMULATION
KW - TRANSITIONS
U2 - 10.1063/1.471089
DO - 10.1063/1.471089
M3 - Journal article
VL - 104
SP - 3234
EP - 3243
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 9
ER -