Dynamic aspects of electronic predissociation

Michael Grønager; Niels Engholm Henriksen

doi:10.1063/1.471089

Dynamic aspects of electronic predissociation

Michael Grønager, Niels Engholm Henriksen

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

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Abstract

We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.

Original language	English
Journal	Journal of Chemical Physics
Volume	104
Issue number	9
Pages (from-to)	3234-3243
ISSN	0021-9606
DOIs	https://doi.org/10.1063/1.471089
Publication status	Published - 1996

Bibliographical note

Copyright (1996) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.

Keywords

FORMULATION
TRANSITIONS

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10.1063/1.471089

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http://link.aip.org/link/?JCPSA6/104/3234/1

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abstract = "We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.",

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AU - Henriksen, Niels Engholm

N1 - Copyright (1996) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.

PY - 1996

Y1 - 1996

N2 - We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.

AB - We consider electronic excitation induced with a continuous wave laser to an excited bound state which can predissociate due to a radiationless transition to a dissociative state. The conditions for a separation of the process into the preparation of a vibrational eigenstate which subsequently dissociates due to a radiationless transition are established. We point out that the probability of the radiationless transition can be calculated from a time-dependent nuclear autocorrelation function, an expression which nicely reflects the pictorial aspect of the Franck-Condon principle. (C) 1996 American Institute of Physics.

KW - FORMULATION

KW - TRANSITIONS

U2 - 10.1063/1.471089

DO - 10.1063/1.471089

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JF - Journal of Chemical Physics

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