Directs measurement of high temperature/high  pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance

Nicolas von Solms; A Rubin; Simon Ivar Andersen; Erling Halfdan Stenby

doi:10.1007/s10765-005-2357-z

Directs measurement of high temperature/high pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance

Nicolas von Solms, A Rubin, Simon Ivar Andersen, Erling Halfdan Stenby

NKT Group

Research output: Contribution to journal › Conference article › Research › peer-review

Abstract

Experiments to determine the Solubility of methane and carbon dioxide in PA-11 have been performed in the temperature range 50-90&DEG; C and the pressure ranges 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, the results agree fairly well with previous experiments for similar polymers, as well as showing correct trends in terms of temperature and pressure. The Solubility of the gases follows Henry's law-type behavior except for methane at very high pressures. Diffusivities were also measured for the same systems at the same conditions. While the diffusivities are subject to more uncertainty than the solubility measurements, the expected (Arrhenius) trends are observed. Agreement with other experimental data using different methods is also good.

Original language	English
Journal	International Journal of Thermophysics
Volume	26
Issue number	1
Pages (from-to)	115-125
ISSN	0195-928X
DOIs	https://doi.org/10.1007/s10765-005-2357-z
Publication status	Published - 2005
Event	Symposium on Thermophysical Properties - Boulder, United States Duration: 22 Jun 2003 → 27 Jun 2003 Conference number: 15

Conference

Conference	Symposium on Thermophysical Properties
Number	15
Country/Territory	United States
City	Boulder
Period	22/06/2003 → 27/06/2003

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@inproceedings{186ab88015684a3ca6c1ef2b2bd603bc,

title = "Directs measurement of high temperature/high pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance",

abstract = "Experiments to determine the Solubility of methane and carbon dioxide in PA-11 have been performed in the temperature range 50-90&DEG; C and the pressure ranges 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, the results agree fairly well with previous experiments for similar polymers, as well as showing correct trends in terms of temperature and pressure. The Solubility of the gases follows Henry's law-type behavior except for methane at very high pressures. Diffusivities were also measured for the same systems at the same conditions. While the diffusivities are subject to more uncertainty than the solubility measurements, the expected (Arrhenius) trends are observed. Agreement with other experimental data using different methods is also good.",

author = "{von Solms}, Nicolas and A Rubin and Andersen, {Simon Ivar} and Stenby, {Erling Halfdan}",

year = "2005",

doi = "10.1007/s10765-005-2357-z",

language = "English",

volume = "26",

pages = "115--125",

journal = "International Journal of Thermophysics",

issn = "0195-928X",

publisher = "Springer New York",

number = "1",

note = "Symposium on Thermophysical Properties, 15th ; Conference date: 22-06-2003 Through 27-06-2003",

}

Directs measurement of high temperature/high pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance. / von Solms, Nicolas; Rubin, A; Andersen, Simon Ivar et al.
In: International Journal of Thermophysics, Vol. 26, No. 1, 2005, p. 115-125.

Research output: Contribution to journal › Conference article › Research › peer-review

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T1 - Directs measurement of high temperature/high pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance

AU - von Solms, Nicolas

AU - Rubin, A

AU - Andersen, Simon Ivar

AU - Stenby, Erling Halfdan

N1 - Conference code: 15

PY - 2005

Y1 - 2005

N2 - Experiments to determine the Solubility of methane and carbon dioxide in PA-11 have been performed in the temperature range 50-90&DEG; C and the pressure ranges 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, the results agree fairly well with previous experiments for similar polymers, as well as showing correct trends in terms of temperature and pressure. The Solubility of the gases follows Henry's law-type behavior except for methane at very high pressures. Diffusivities were also measured for the same systems at the same conditions. While the diffusivities are subject to more uncertainty than the solubility measurements, the expected (Arrhenius) trends are observed. Agreement with other experimental data using different methods is also good.

AB - Experiments to determine the Solubility of methane and carbon dioxide in PA-11 have been performed in the temperature range 50-90&DEG; C and the pressure ranges 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, the results agree fairly well with previous experiments for similar polymers, as well as showing correct trends in terms of temperature and pressure. The Solubility of the gases follows Henry's law-type behavior except for methane at very high pressures. Diffusivities were also measured for the same systems at the same conditions. While the diffusivities are subject to more uncertainty than the solubility measurements, the expected (Arrhenius) trends are observed. Agreement with other experimental data using different methods is also good.

U2 - 10.1007/s10765-005-2357-z

DO - 10.1007/s10765-005-2357-z

M3 - Conference article

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VL - 26

SP - 115

EP - 125

JO - International Journal of Thermophysics

JF - International Journal of Thermophysics

IS - 1

T2 - Symposium on Thermophysical Properties

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