Direct aerobic oxidation of primary alcohols to methyl esters catalyzed by a heterogeneous gold catalyst

Inger Staunstrup Nielsen, Esben Taarning, Kresten Egeblad, Robert Madsen, Claus H. Christensen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Methyl esters can be produced in high yield by oxidising methanolic solutions of primary alcohols with dioxygen over a heterogeneous gold catalyst. The versatility of this new methodology is demonstrated by the fact that alkylic, benzylic and allylic alcohols, as well as alcohols containing an amine functionality are oxidized in good to excellent yield.
Original languageEnglish
JournalCatalysis Letters
Volume116
Issue number1-2
Pages (from-to)35-40
ISSN1011-372X
DOIs
Publication statusPublished - 2007

Keywords

  • Gold catalysis
  • Catalytic oxidations
  • Air
  • Ester synthesis
  • Methyl esters

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