Design of Monovalent Ion Selective Membranes for Reducing the Impacts of Multivalent Ions in Reverse Electrodialysis

Abreham Tesfaye Besha, Misgina Tilahun Tsehaye, David Aili, Wenjuan Zhang, Ramato Ashu Tufa*

*Corresponding author for this work

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Abstract

Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are systematically reviewed along with possible strategies to overcome this challenge. In particular, the use of monovalent ion-selective membranes represents a promising alternative to reduce the negative impact of multivalent ions given the availability of low-cost materials and an easy route of membrane synthesis. A thorough assessment of the materials and methodologies used to prepare monovalent selective ion exchange membranes (both cation and anion exchange membranes) for applications in (reverse) electrodialysis is performed. Moreover, transport mechanisms under conditions of extreme salinity gradient are analyzed and compared for a better understanding of the design criteria. The ultimate goal of the present work is to propose a prospective research direction on the development of new membrane materials for effective implementation of RED under natural feed conditions.
Original languageEnglish
Article number7
JournalMembranes
Volume10
Issue number1
Number of pages28
ISSN2077-0375
DOIs
Publication statusPublished - 2019

Cite this

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title = "Design of Monovalent Ion Selective Membranes for Reducing the Impacts of Multivalent Ions in Reverse Electrodialysis",
abstract = "Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are systematically reviewed along with possible strategies to overcome this challenge. In particular, the use of monovalent ion-selective membranes represents a promising alternative to reduce the negative impact of multivalent ions given the availability of low-cost materials and an easy route of membrane synthesis. A thorough assessment of the materials and methodologies used to prepare monovalent selective ion exchange membranes (both cation and anion exchange membranes) for applications in (reverse) electrodialysis is performed. Moreover, transport mechanisms under conditions of extreme salinity gradient are analyzed and compared for a better understanding of the design criteria. The ultimate goal of the present work is to propose a prospective research direction on the development of new membrane materials for effective implementation of RED under natural feed conditions.",
author = "Besha, {Abreham Tesfaye} and Tsehaye, {Misgina Tilahun} and David Aili and Wenjuan Zhang and Tufa, {Ramato Ashu}",
year = "2019",
doi = "10.3390/membranes10010007",
language = "English",
volume = "10",
journal = "Membranes",
issn = "2077-0375",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
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Design of Monovalent Ion Selective Membranes for Reducing the Impacts of Multivalent Ions in Reverse Electrodialysis. / Besha, Abreham Tesfaye; Tsehaye, Misgina Tilahun; Aili, David; Zhang, Wenjuan; Tufa, Ramato Ashu.

In: Membranes, Vol. 10, No. 1, 7, 2019.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Design of Monovalent Ion Selective Membranes for Reducing the Impacts of Multivalent Ions in Reverse Electrodialysis

AU - Besha, Abreham Tesfaye

AU - Tsehaye, Misgina Tilahun

AU - Aili, David

AU - Zhang, Wenjuan

AU - Tufa, Ramato Ashu

PY - 2019

Y1 - 2019

N2 - Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are systematically reviewed along with possible strategies to overcome this challenge. In particular, the use of monovalent ion-selective membranes represents a promising alternative to reduce the negative impact of multivalent ions given the availability of low-cost materials and an easy route of membrane synthesis. A thorough assessment of the materials and methodologies used to prepare monovalent selective ion exchange membranes (both cation and anion exchange membranes) for applications in (reverse) electrodialysis is performed. Moreover, transport mechanisms under conditions of extreme salinity gradient are analyzed and compared for a better understanding of the design criteria. The ultimate goal of the present work is to propose a prospective research direction on the development of new membrane materials for effective implementation of RED under natural feed conditions.

AB - Reverse electrodialysis (RED) represents one of the most promising membrane-based technologies for clean and renewable energy production from mixing water solutions. However, the presence of multivalent ions in natural water drastically reduces system performance, in particular, the open-circuit voltage (OCV) and the output power. This effect is largely described by the “uphill transport” phenomenon, in which multivalent ions are transported against the concentration gradient. In this work, recent advances in the investigation of the impact of multivalent ions on power generation by RED are systematically reviewed along with possible strategies to overcome this challenge. In particular, the use of monovalent ion-selective membranes represents a promising alternative to reduce the negative impact of multivalent ions given the availability of low-cost materials and an easy route of membrane synthesis. A thorough assessment of the materials and methodologies used to prepare monovalent selective ion exchange membranes (both cation and anion exchange membranes) for applications in (reverse) electrodialysis is performed. Moreover, transport mechanisms under conditions of extreme salinity gradient are analyzed and compared for a better understanding of the design criteria. The ultimate goal of the present work is to propose a prospective research direction on the development of new membrane materials for effective implementation of RED under natural feed conditions.

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