Densification of Ce0.9Gd0.1O1.95 barrier layer by in-situ solid state reaction

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

A novel methodology, called in-situ solid state reaction (SSR), is developed and achieved for the densification of gadolinia doped ceria (CGO) barrier layer (BL) within the solid oxide fuel cell (SOFC) technology. The method is based on the combined use of impregnation technique and a designed two-step sintering process to promote the densification of the CGO-BL on dense yttria stabilized zirconia (YSZ) electrolyte. A pre-sintering step is carried out at temperature T1 (1150e1250 °C) to obtain porous and interconnected CGO-BL on dense electrolyte substrate. Impregnation of the porous BL is then carried out with small amount of either cobalt or copper nitrate solutions as sintering aids. Final sintering of the CGO-BL at temperature T2 (1250e1275 _C, T2 > T1) is used to promote an SSR between the sintering aid and CGO-BL to obtain densification and grain growth. The approach proposed in this work was proved on both screen printed and tape cast CGO-BL, showing feasibility for the densification of generic ceramic multilayer systems undergoing different constrained sintering conditions and for a large variety of materials.
© 2014 Elsevier B.V. All rights reserved.
Original languageEnglish
JournalJournal of Power Sources
Volume266
Pages (from-to)393-400
ISSN0378-7753
DOIs
Publication statusPublished - 2014

Keywords

  • Sintering
  • CGO
  • sOfc
  • Multilayer ceramics

Cite this

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title = "Densification of Ce0.9Gd0.1O1.95 barrier layer by in-situ solid state reaction",
abstract = "A novel methodology, called in-situ solid state reaction (SSR), is developed and achieved for the densification of gadolinia doped ceria (CGO) barrier layer (BL) within the solid oxide fuel cell (SOFC) technology. The method is based on the combined use of impregnation technique and a designed two-step sintering process to promote the densification of the CGO-BL on dense yttria stabilized zirconia (YSZ) electrolyte. A pre-sintering step is carried out at temperature T1 (1150e1250 °C) to obtain porous and interconnected CGO-BL on dense electrolyte substrate. Impregnation of the porous BL is then carried out with small amount of either cobalt or copper nitrate solutions as sintering aids. Final sintering of the CGO-BL at temperature T2 (1250e1275 _C, T2 > T1) is used to promote an SSR between the sintering aid and CGO-BL to obtain densification and grain growth. The approach proposed in this work was proved on both screen printed and tape cast CGO-BL, showing feasibility for the densification of generic ceramic multilayer systems undergoing different constrained sintering conditions and for a large variety of materials.{\circledC} 2014 Elsevier B.V. All rights reserved.",
keywords = "Sintering, CGO, sOfc, Multilayer ceramics",
author = "Ni, {De Wei} and Vincenzo Esposito",
year = "2014",
doi = "10.1016/j.jpowsour.2014.05.044",
language = "English",
volume = "266",
pages = "393--400",
journal = "Journal of Power Sources",
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}

Densification of Ce0.9Gd0.1O1.95 barrier layer by in-situ solid state reaction. / Ni, De Wei; Esposito, Vincenzo.

In: Journal of Power Sources, Vol. 266, 2014, p. 393-400.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Densification of Ce0.9Gd0.1O1.95 barrier layer by in-situ solid state reaction

AU - Ni, De Wei

AU - Esposito, Vincenzo

PY - 2014

Y1 - 2014

N2 - A novel methodology, called in-situ solid state reaction (SSR), is developed and achieved for the densification of gadolinia doped ceria (CGO) barrier layer (BL) within the solid oxide fuel cell (SOFC) technology. The method is based on the combined use of impregnation technique and a designed two-step sintering process to promote the densification of the CGO-BL on dense yttria stabilized zirconia (YSZ) electrolyte. A pre-sintering step is carried out at temperature T1 (1150e1250 °C) to obtain porous and interconnected CGO-BL on dense electrolyte substrate. Impregnation of the porous BL is then carried out with small amount of either cobalt or copper nitrate solutions as sintering aids. Final sintering of the CGO-BL at temperature T2 (1250e1275 _C, T2 > T1) is used to promote an SSR between the sintering aid and CGO-BL to obtain densification and grain growth. The approach proposed in this work was proved on both screen printed and tape cast CGO-BL, showing feasibility for the densification of generic ceramic multilayer systems undergoing different constrained sintering conditions and for a large variety of materials.© 2014 Elsevier B.V. All rights reserved.

AB - A novel methodology, called in-situ solid state reaction (SSR), is developed and achieved for the densification of gadolinia doped ceria (CGO) barrier layer (BL) within the solid oxide fuel cell (SOFC) technology. The method is based on the combined use of impregnation technique and a designed two-step sintering process to promote the densification of the CGO-BL on dense yttria stabilized zirconia (YSZ) electrolyte. A pre-sintering step is carried out at temperature T1 (1150e1250 °C) to obtain porous and interconnected CGO-BL on dense electrolyte substrate. Impregnation of the porous BL is then carried out with small amount of either cobalt or copper nitrate solutions as sintering aids. Final sintering of the CGO-BL at temperature T2 (1250e1275 _C, T2 > T1) is used to promote an SSR between the sintering aid and CGO-BL to obtain densification and grain growth. The approach proposed in this work was proved on both screen printed and tape cast CGO-BL, showing feasibility for the densification of generic ceramic multilayer systems undergoing different constrained sintering conditions and for a large variety of materials.© 2014 Elsevier B.V. All rights reserved.

KW - Sintering

KW - CGO

KW - sOfc

KW - Multilayer ceramics

U2 - 10.1016/j.jpowsour.2014.05.044

DO - 10.1016/j.jpowsour.2014.05.044

M3 - Journal article

VL - 266

SP - 393

EP - 400

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

ER -