Dehydrogenative Coupling of Primary Alcohols To Form Esters Catalyzed by a Ruthenium N-Heterocyclic Carbene Complex

Amanda Birgitte Sølvhøj; Robert Madsen

doi:10.1021/om200928b

Dehydrogenative Coupling of Primary Alcohols To Form Esters Catalyzed by a Ruthenium N-Heterocyclic Carbene Complex

Amanda Birgitte Sølvhøj, Robert Madsen

Department of Chemistry

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Abstract

The ruthenium complex [RuCl2(IiPr)(p-cymene)] catalyzes the direct condensation of primary alcohols into esters and lactones with the release of hydrogen gas. The reaction is most effective with linear aliphatic alcohols and 1,4-diols and is believed to proceed with a ruthenium dihydride as the catalytically active species.

Original language	English
Journal	Organometallics
Volume	30
Pages (from-to)	6044-6048
ISSN	0276-7333
DOIs	https://doi.org/10.1021/om200928b
Publication status	Published - 2011

Bibliographical note

Acknowledgement: We thank the Danish Council for Independent Research—Technology and Production Sciences for financial support.

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title = "Dehydrogenative Coupling of Primary Alcohols To Form Esters Catalyzed by a Ruthenium N-Heterocyclic Carbene Complex",

abstract = "The ruthenium complex [RuCl2(IiPr)(p-cymene)] catalyzes the direct condensation of primary alcohols into esters and lactones with the release of hydrogen gas. The reaction is most effective with linear aliphatic alcohols and 1,4-diols and is believed to proceed with a ruthenium dihydride as the catalytically active species.",

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AU - Sølvhøj, Amanda Birgitte

AU - Madsen, Robert

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N2 - The ruthenium complex [RuCl2(IiPr)(p-cymene)] catalyzes the direct condensation of primary alcohols into esters and lactones with the release of hydrogen gas. The reaction is most effective with linear aliphatic alcohols and 1,4-diols and is believed to proceed with a ruthenium dihydride as the catalytically active species.

AB - The ruthenium complex [RuCl2(IiPr)(p-cymene)] catalyzes the direct condensation of primary alcohols into esters and lactones with the release of hydrogen gas. The reaction is most effective with linear aliphatic alcohols and 1,4-diols and is believed to proceed with a ruthenium dihydride as the catalytically active species.

U2 - 10.1021/om200928b

DO - 10.1021/om200928b

M3 - Journal article

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JO - Organometallics

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ER -

Dehydrogenative Coupling of Primary Alcohols To Form Esters Catalyzed by a Ruthenium N-Heterocyclic Carbene Complex

Abstract

Bibliographical note

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