Defect chemistry and oxygen transport of (La0.6Sr0.4-xMx)(0.99)Co0.2Fe0.8O3-delta, M = Ca (x=0.05, 0.1), Ba (x=0.1, 0.2), Sr Part I: Defect chemistry

Bjarke Thomas Dalslet, Martin Søgaard, Henry J.M. Bouwmeester, Peter Vang Hendriksen

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    This paper is the first part of a two part series, where the effects of varying the A-site dopant on the defect chemistry, the diffusion coefficient and the surface catalytic properties of the materials (La0.6Sr0.4 − xMx)0.99Co0.2Fe0.8O3 − δ, M = Sr, Ca (x = 0.05, 0.1), Ba (x = 0.1, 0.2) (LSMFC) have been investigated. In part I, the findings on the defect chemistry are reported, while the transport properties are reported in part II. Substitution of Sr2+ ions with Ca2+ ions (smaller ionic radius) and Ba2+ ions (larger ionic radius) strains the crystal structure differently for each composition while keeping the average valence of the cations constant. The Ba2+ containing materials show the largest oxygen loss at elevated temperatures, while the purely Sr2+ doped material showed the smallest oxygen loss. This was reflected in the partial oxidation entropy of the materials. The measured oxygen loss was modelled with point defect chemistry models. Measurements at very low pO2 showed several phase transitions.
    Original languageEnglish
    JournalSolid State Ionics
    Volume180
    Issue number20-22
    Pages (from-to)1173-1182
    ISSN0167-2738
    DOIs
    Publication statusPublished - 2009

    Keywords

    • Fuel Cells and hydrogen
    • Ceramic Membranes
    • Membraner

    Cite this

    @article{46ed66fdb6ca4091b5d333d1e556964e,
    title = "Defect chemistry and oxygen transport of (La0.6Sr0.4-xMx)(0.99)Co0.2Fe0.8O3-delta, M = Ca (x=0.05, 0.1), Ba (x=0.1, 0.2), Sr Part I: Defect chemistry",
    abstract = "This paper is the first part of a two part series, where the effects of varying the A-site dopant on the defect chemistry, the diffusion coefficient and the surface catalytic properties of the materials (La0.6Sr0.4 − xMx)0.99Co0.2Fe0.8O3 − δ, M = Sr, Ca (x = 0.05, 0.1), Ba (x = 0.1, 0.2) (LSMFC) have been investigated. In part I, the findings on the defect chemistry are reported, while the transport properties are reported in part II. Substitution of Sr2+ ions with Ca2+ ions (smaller ionic radius) and Ba2+ ions (larger ionic radius) strains the crystal structure differently for each composition while keeping the average valence of the cations constant. The Ba2+ containing materials show the largest oxygen loss at elevated temperatures, while the purely Sr2+ doped material showed the smallest oxygen loss. This was reflected in the partial oxidation entropy of the materials. The measured oxygen loss was modelled with point defect chemistry models. Measurements at very low pO2 showed several phase transitions.",
    keywords = "Fuel Cells and hydrogen, Ceramic Membranes, Membraner, Br{\ae}ndselsceller og brint",
    author = "Dalslet, {Bjarke Thomas} and Martin S{\o}gaard and Bouwmeester, {Henry J.M.} and Hendriksen, {Peter Vang}",
    year = "2009",
    doi = "10.1016/j.ssi.2009.05.011",
    language = "English",
    volume = "180",
    pages = "1173--1182",
    journal = "Solid State Ionics",
    issn = "0167-2738",
    publisher = "Elsevier",
    number = "20-22",

    }

    Defect chemistry and oxygen transport of (La0.6Sr0.4-xMx)(0.99)Co0.2Fe0.8O3-delta, M = Ca (x=0.05, 0.1), Ba (x=0.1, 0.2), Sr Part I: Defect chemistry. / Dalslet, Bjarke Thomas; Søgaard, Martin; Bouwmeester, Henry J.M.; Hendriksen, Peter Vang.

    In: Solid State Ionics, Vol. 180, No. 20-22, 2009, p. 1173-1182.

    Research output: Contribution to journalJournal articleResearchpeer-review

    TY - JOUR

    T1 - Defect chemistry and oxygen transport of (La0.6Sr0.4-xMx)(0.99)Co0.2Fe0.8O3-delta, M = Ca (x=0.05, 0.1), Ba (x=0.1, 0.2), Sr Part I: Defect chemistry

    AU - Dalslet, Bjarke Thomas

    AU - Søgaard, Martin

    AU - Bouwmeester, Henry J.M.

    AU - Hendriksen, Peter Vang

    PY - 2009

    Y1 - 2009

    N2 - This paper is the first part of a two part series, where the effects of varying the A-site dopant on the defect chemistry, the diffusion coefficient and the surface catalytic properties of the materials (La0.6Sr0.4 − xMx)0.99Co0.2Fe0.8O3 − δ, M = Sr, Ca (x = 0.05, 0.1), Ba (x = 0.1, 0.2) (LSMFC) have been investigated. In part I, the findings on the defect chemistry are reported, while the transport properties are reported in part II. Substitution of Sr2+ ions with Ca2+ ions (smaller ionic radius) and Ba2+ ions (larger ionic radius) strains the crystal structure differently for each composition while keeping the average valence of the cations constant. The Ba2+ containing materials show the largest oxygen loss at elevated temperatures, while the purely Sr2+ doped material showed the smallest oxygen loss. This was reflected in the partial oxidation entropy of the materials. The measured oxygen loss was modelled with point defect chemistry models. Measurements at very low pO2 showed several phase transitions.

    AB - This paper is the first part of a two part series, where the effects of varying the A-site dopant on the defect chemistry, the diffusion coefficient and the surface catalytic properties of the materials (La0.6Sr0.4 − xMx)0.99Co0.2Fe0.8O3 − δ, M = Sr, Ca (x = 0.05, 0.1), Ba (x = 0.1, 0.2) (LSMFC) have been investigated. In part I, the findings on the defect chemistry are reported, while the transport properties are reported in part II. Substitution of Sr2+ ions with Ca2+ ions (smaller ionic radius) and Ba2+ ions (larger ionic radius) strains the crystal structure differently for each composition while keeping the average valence of the cations constant. The Ba2+ containing materials show the largest oxygen loss at elevated temperatures, while the purely Sr2+ doped material showed the smallest oxygen loss. This was reflected in the partial oxidation entropy of the materials. The measured oxygen loss was modelled with point defect chemistry models. Measurements at very low pO2 showed several phase transitions.

    KW - Fuel Cells and hydrogen

    KW - Ceramic Membranes

    KW - Membraner

    KW - Brændselsceller og brint

    U2 - 10.1016/j.ssi.2009.05.011

    DO - 10.1016/j.ssi.2009.05.011

    M3 - Journal article

    VL - 180

    SP - 1173

    EP - 1182

    JO - Solid State Ionics

    JF - Solid State Ionics

    SN - 0167-2738

    IS - 20-22

    ER -