Deciphering anthropogenic uranium sources in the equatorial northwest Pacific margin

This work reports the first high-resolution deposition records of anthropogenic uranium (²³⁶U and ²³³U) in a sediment core taken at the continental slope of the Philippine Sea off Mindanao Island in the equatorial northwest Pacific Ocean. Two notable peaks were observed in both profiles of ²³⁶U and ²³³U concentrations, with a narrower peak in 1951–1957 corresponding to close-in Pacific Proving Grounds (PPG) signal, and a broader peak in 1960s–1980s corresponding to the global fallout from nuclear weapons testing. ²³⁶U and ²³³U areal cumulative inventories in the studied sediment core are (2.79 ± 0.20) ∙ 10¹² atom ∙ m⁻² and (3.12 ± 0.41) ∙ 10¹⁰ atom ∙ m⁻², respectively, about 20–30% of reported ²³³U and ²³⁶U inventories from the direct global fallout deposition. The overall ²³³U/²³⁶U atomic ratios obtained in this work vary within (0.3–3.5) ∙ 10⁻², with an integrated ²³³U/²³⁶U atomic ratio of (1.12 ± 0.17) ∙ 10⁻². The contribution from global fallout and close-in PPG fallout to ²³⁶U in the sediment core is estimated to be about 69% and 31%, respectively. We believe the main driving process for anthropogenic uranium deposition in the Philippine sediment is continuous scavenging of dissolved ²³⁶U from the surface seawater by sinking particles.