TY - JOUR
T1 - CVD Graphene/Ni Interface Evolution in Sulfuric Electrolyte
AU - Yivlialin, Rossella
AU - Bussetti, Gianlorenzo
AU - Duò, Lamberto
AU - Yu, Feng
AU - Galbiati, Miriam
AU - Camilli, Luca
PY - 2018
Y1 - 2018
N2 - Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified.
AB - Systems comprising single and multilayer graphene deposited on metals and immersed in acid environments have been investigated, with the aim of elucidating the mechanisms involved, for instance, in hydrogen production or metal protection from corrosion. In this work, a relevant system, namely chemical vapor deposited (CVD) multilayer graphene/Ni (MLGr/Ni), is studied when immersed in a diluted sulfuric electrolyte. The MLGr/Ni electrochemical and morphological properties are studied in situ and interpreted in light of the highly oriented pyrolytic graphite (HOPG) electrode behavior, when immersed in the same electrolyte. Following this interpretative framework, the dominant role of the Ni substrate in hydrogen production is clarified.
U2 - 10.1021/acs.langmuir.8b00459
DO - 10.1021/acs.langmuir.8b00459
M3 - Journal article
C2 - 29485887
SN - 0743-7463
VL - 34
SP - 3413
EP - 3419
JO - Langmuir
JF - Langmuir
IS - 11
ER -
