Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition

Marina Kustova; Arkadii Kustov; Sofie E. Christiansen; Karen Thrane Leth; Søren Birk Rasmussen; Claus H. Christensen

doi:10.1016/j.catcom.2006.02.019

Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition

Marina Kustova, Arkadii Kustov, Sofie E. Christiansen, Karen Thrane Leth, Søren Birk Rasmussen, Claus H. Christensen

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Cu-ZSM-5 has for many years been recognized as a unique catalyst for direct NO decomposition. Here, it is discovered that both Cu-ZSM-11 and Cu-ZSM-12 are about twice as active as Cu-ZSM-5. This difference is attributed to the active sites located almost exclusively in the straight zeolite pores. In situ EPR results suggest that higher activity is related with improved accessibility of these sites. Thus, it is clear that contrary to previous observations, the special pore structure of Cu-ZSM-5 is not a decisive factor for catalytic activity in NO decomposition. (c) 2006 Elsevier B.V. All rights reserved.

Original language	English
Journal	Catalysis Communications
Volume	7
Issue number	9
Pages (from-to)	705-708
ISSN	1566-7367
DOIs	https://doi.org/10.1016/j.catcom.2006.02.019
Publication status	Published - 2006

Keywords

NO decomposition
Catalysis
Zeolite
Copper
Pore architecture

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10.1016/j.catcom.2006.02.019

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@article{e41caaccd8fc40bd8de808eaf014c9b5,

title = "Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition",

abstract = "Cu-ZSM-5 has for many years been recognized as a unique catalyst for direct NO decomposition. Here, it is discovered that both Cu-ZSM-11 and Cu-ZSM-12 are about twice as active as Cu-ZSM-5. This difference is attributed to the active sites located almost exclusively in the straight zeolite pores. In situ EPR results suggest that higher activity is related with improved accessibility of these sites. Thus, it is clear that contrary to previous observations, the special pore structure of Cu-ZSM-5 is not a decisive factor for catalytic activity in NO decomposition. (c) 2006 Elsevier B.V. All rights reserved. ",

keywords = "NO decomposition, Catalysis, Zeolite, Copper, Pore architecture",

author = "Marina Kustova and Arkadii Kustov and Christiansen, {Sofie E.} and Leth, {Karen Thrane} and Rasmussen, {S{\o}ren Birk} and Christensen, {Claus H.}",

year = "2006",

doi = "10.1016/j.catcom.2006.02.019",

language = "English",

volume = "7",

pages = "705--708",

journal = "Catalysis Communications",

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TY - JOUR

T1 - Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition

AU - Kustova, Marina

AU - Kustov, Arkadii

AU - Christiansen, Sofie E.

AU - Leth, Karen Thrane

AU - Rasmussen, Søren Birk

AU - Christensen, Claus H.

PY - 2006

Y1 - 2006

N2 - Cu-ZSM-5 has for many years been recognized as a unique catalyst for direct NO decomposition. Here, it is discovered that both Cu-ZSM-11 and Cu-ZSM-12 are about twice as active as Cu-ZSM-5. This difference is attributed to the active sites located almost exclusively in the straight zeolite pores. In situ EPR results suggest that higher activity is related with improved accessibility of these sites. Thus, it is clear that contrary to previous observations, the special pore structure of Cu-ZSM-5 is not a decisive factor for catalytic activity in NO decomposition. (c) 2006 Elsevier B.V. All rights reserved.

AB - Cu-ZSM-5 has for many years been recognized as a unique catalyst for direct NO decomposition. Here, it is discovered that both Cu-ZSM-11 and Cu-ZSM-12 are about twice as active as Cu-ZSM-5. This difference is attributed to the active sites located almost exclusively in the straight zeolite pores. In situ EPR results suggest that higher activity is related with improved accessibility of these sites. Thus, it is clear that contrary to previous observations, the special pore structure of Cu-ZSM-5 is not a decisive factor for catalytic activity in NO decomposition. (c) 2006 Elsevier B.V. All rights reserved.

KW - NO decomposition

KW - Catalysis

KW - Zeolite

KW - Copper

KW - Pore architecture

U2 - 10.1016/j.catcom.2006.02.019

DO - 10.1016/j.catcom.2006.02.019

M3 - Journal article

SN - 1566-7367

VL - 7

SP - 705

EP - 708

JO - Catalysis Communications

JF - Catalysis Communications

IS - 9

ER -

Cu-ZSM-5, Cu-ZSM-11, and Cu-ZSM-12 Catalysts for Direct NO Decomposition

Abstract

Keywords

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