Cost-efficient microbial electrosynthesis of hydrogen peroxide on a facile-prepared floating electrode by entrapping oxygen

Microbial electrosynthesis of hydrogen peroxide is receiving growing interest for a green substitute for anthraquinone process. However, poor oxygen transmission of electrode remains an obstacle to enhance H₂O₂ production rate without aeration. Here, a superhydrophobic natural air diffusion floating electrode (NADFE), which naturally and efficiently entraps O₂ in the air, was proposed for the first time to improve microbial electrosynthesis of H₂O₂. Furthermore, a one-step calcined electrode preparation method was developed to reduce energy consumption further. In the microbial electrolysis cell with the NADFE, a high H₂O₂ production rate of 39 mg/L/h and current efficiency of 86% were achieved without aeration. The production rate of H₂O₂ was 2.2 times that of a gas diffusion electrode. Importantly, the energy consumption was 34.3 times lower than an electrochemical system. Therefore, the high H₂O₂ production rate and current efficiency, and low energy consumption of the process provide a superior alternative for environmental remediation.