Corrosion protection of AA2024-T3 alloy by modified hybrid titania-containing sol-gel coatings

Feng Yu, Robert Akid

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

In this study, a hybrid titania-containing sol-gel coating, designated the ‘standard system’, has beenmodified through additions of a co-polymer polyvinyl butyral (PVB), a conductive polymer polyaniline(PANI) and a corrosion resistant glass flake (GF) to investigate the influence of these pigments for thecorrosion protection of AA2024-T3 alloy. Electrochemical impedance spectroscopy (EIS) was conductedon these coatings during immersion in 3.5% NaCl solution. Results revealed that modification by PVB ina volume ratio of sol-gel/PVB = 4:1 can increase the resistance to electrolyte ingress of the sol-gel layer,whilst the PANI in agglomerate-type particles produced a chemically stable intermediate layer betweenthe coating and substrate. Additionally, physical barrier properties to water uptake are provided by themodification of the sol-gel with GF. Differential scanning calorimetry and thermogravimetry (DSC/TG)analysis and water contact angle measurements indicated that GF increases the thermal stability and decreases the hydrophobicity. Both properties are improved by modification of PANI and reduced byaddition of PVB. Cross-hatch adhesion tests showed high adhesion strength between all the coatings on AA2024-T3 alloy. Fourier transformed infrared spectroscopy (FTIR) analysis suggested that PVB affected the condensation reactions taking place during the sol-gel synthesis.
Original languageEnglish
JournalProgress in Organic Coatings
Volume102
Pages (from-to)120-129
Number of pages10
ISSN0300-9440
DOIs
Publication statusPublished - 2017
Externally publishedYes

Cite this

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title = "Corrosion protection of AA2024-T3 alloy by modified hybrid titania-containing sol-gel coatings",
abstract = "In this study, a hybrid titania-containing sol-gel coating, designated the ‘standard system’, has beenmodified through additions of a co-polymer polyvinyl butyral (PVB), a conductive polymer polyaniline(PANI) and a corrosion resistant glass flake (GF) to investigate the influence of these pigments for thecorrosion protection of AA2024-T3 alloy. Electrochemical impedance spectroscopy (EIS) was conductedon these coatings during immersion in 3.5{\%} NaCl solution. Results revealed that modification by PVB ina volume ratio of sol-gel/PVB = 4:1 can increase the resistance to electrolyte ingress of the sol-gel layer,whilst the PANI in agglomerate-type particles produced a chemically stable intermediate layer betweenthe coating and substrate. Additionally, physical barrier properties to water uptake are provided by themodification of the sol-gel with GF. Differential scanning calorimetry and thermogravimetry (DSC/TG)analysis and water contact angle measurements indicated that GF increases the thermal stability and decreases the hydrophobicity. Both properties are improved by modification of PANI and reduced byaddition of PVB. Cross-hatch adhesion tests showed high adhesion strength between all the coatings on AA2024-T3 alloy. Fourier transformed infrared spectroscopy (FTIR) analysis suggested that PVB affected the condensation reactions taking place during the sol-gel synthesis.",
author = "Feng Yu and Robert Akid",
year = "2017",
doi = "10.1016/j.porgcoat.2016.09.022",
language = "English",
volume = "102",
pages = "120--129",
journal = "Progress in Organic Coatings",
issn = "0300-9440",
publisher = "Elsevier",

}

Corrosion protection of AA2024-T3 alloy by modified hybrid titania-containing sol-gel coatings. / Yu, Feng; Akid, Robert.

In: Progress in Organic Coatings, Vol. 102, 2017, p. 120-129.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Corrosion protection of AA2024-T3 alloy by modified hybrid titania-containing sol-gel coatings

AU - Yu, Feng

AU - Akid, Robert

PY - 2017

Y1 - 2017

N2 - In this study, a hybrid titania-containing sol-gel coating, designated the ‘standard system’, has beenmodified through additions of a co-polymer polyvinyl butyral (PVB), a conductive polymer polyaniline(PANI) and a corrosion resistant glass flake (GF) to investigate the influence of these pigments for thecorrosion protection of AA2024-T3 alloy. Electrochemical impedance spectroscopy (EIS) was conductedon these coatings during immersion in 3.5% NaCl solution. Results revealed that modification by PVB ina volume ratio of sol-gel/PVB = 4:1 can increase the resistance to electrolyte ingress of the sol-gel layer,whilst the PANI in agglomerate-type particles produced a chemically stable intermediate layer betweenthe coating and substrate. Additionally, physical barrier properties to water uptake are provided by themodification of the sol-gel with GF. Differential scanning calorimetry and thermogravimetry (DSC/TG)analysis and water contact angle measurements indicated that GF increases the thermal stability and decreases the hydrophobicity. Both properties are improved by modification of PANI and reduced byaddition of PVB. Cross-hatch adhesion tests showed high adhesion strength between all the coatings on AA2024-T3 alloy. Fourier transformed infrared spectroscopy (FTIR) analysis suggested that PVB affected the condensation reactions taking place during the sol-gel synthesis.

AB - In this study, a hybrid titania-containing sol-gel coating, designated the ‘standard system’, has beenmodified through additions of a co-polymer polyvinyl butyral (PVB), a conductive polymer polyaniline(PANI) and a corrosion resistant glass flake (GF) to investigate the influence of these pigments for thecorrosion protection of AA2024-T3 alloy. Electrochemical impedance spectroscopy (EIS) was conductedon these coatings during immersion in 3.5% NaCl solution. Results revealed that modification by PVB ina volume ratio of sol-gel/PVB = 4:1 can increase the resistance to electrolyte ingress of the sol-gel layer,whilst the PANI in agglomerate-type particles produced a chemically stable intermediate layer betweenthe coating and substrate. Additionally, physical barrier properties to water uptake are provided by themodification of the sol-gel with GF. Differential scanning calorimetry and thermogravimetry (DSC/TG)analysis and water contact angle measurements indicated that GF increases the thermal stability and decreases the hydrophobicity. Both properties are improved by modification of PANI and reduced byaddition of PVB. Cross-hatch adhesion tests showed high adhesion strength between all the coatings on AA2024-T3 alloy. Fourier transformed infrared spectroscopy (FTIR) analysis suggested that PVB affected the condensation reactions taking place during the sol-gel synthesis.

U2 - 10.1016/j.porgcoat.2016.09.022

DO - 10.1016/j.porgcoat.2016.09.022

M3 - Journal article

VL - 102

SP - 120

EP - 129

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

SN - 0300-9440

ER -