Abstract
We show, theoretically, that the measured effective dispersive and polar surface energies of a heterogeneous Surface are correlated; the correlation, however, differs whether a Cassic or an Israelachvili and Gee model is assumed. Fluorocarbon self-assembled monolayers with varying coverage were grown oil oxidized (100) silicon Surfaces in a vapor phase process using five different precursors. Experimentally, effective surface energy components of the fluorocarbon self-assembled monolayers were determined from measured contact angles using the Owens-Wendt-Rabel-Kaelble method. We show that the correlation between the effective surface energy components of the heterogeneous Surfaces coated with fluorocarbon self-assembled monolayers is in agreement with the Cassie model.
Original language | English |
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Journal | Langmuir |
Volume | 25 |
Issue number | 10 |
Pages (from-to) | 5437-5441 |
ISSN | 0743-7463 |
DOIs | |
Publication status | Published - 2009 |