Copper oxide as efficient catalyst for oxidative dehydrogenation of alcohols with air

Research output: Contribution to journalJournal article – Annual report year: 2015Researchpeer-review

View graph of relations

The oxidative dehydrogenation of alcohols to carbonyl compounds was studied using CuO nanoparticle catalysts prepared by solution synthesis in buffered media. CuO nanoparticles synthesized in N-cyclohexyl- 3-aminopropanesulfonic acid buffer showed high catalytic activity for the oxidation of benzylic, alicyclic and unsaturated alcohols to their corresponding carbonyl compounds with excellent selectivities. The observed trend in activity for conversion of substituted alcohols suggested a β-H elimination step to be involved, thus enabling a possible reaction mechanism for oxidative dehydrogenation of benzyl alcohols to be proposed. The use of CuO as an inexpensive and efficient heterogeneous catalyst under aerobic conditions provides a new noble metal-free and green reaction protocol for carbonyl compound synthesis.
Original languageEnglish
JournalCatalysis Science & Technology
Volume5
Issue number4
Pages (from-to)2467-2477
Number of pages11
ISSN2044-4753
DOIs
Publication statusPublished - 2015
CitationsWeb of Science® Times Cited: No match on DOI

Download statistics

No data available

ID: 106601503