Copper is highly effective for the epoxidation of a "difficult" alkene, whereas silver is not

R.L. Cropley; F.J. Williams; O.P.H. Vaughan; Andrew Urquhart; M.S. Tikhov; R.M. Lambert

doi:10.1016/j.susc.2005.01.024

Copper is highly effective for the epoxidation of a "difficult" alkene, whereas silver is not

R.L. Cropley, F.J. Williams, O.P.H. Vaughan, Andrew Urquhart, M.S. Tikhov, R.M. Lambert

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

trans-Methyl styrene, an alkene that contains readily abstractable allylic H atoms, adsorbs with very similar conformations on oxygenated single crystal surfaces of Cu and Ag. Strikingly, however, subsequent reaction on silver leads merely to combustion of the organic molecule, whereas copper is extremely effective in catalyzing the epoxidation of this "difficult" alkene. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Journal	Surface Science
Volume	578
Issue number	1-3
Pages (from-to)	L85-L88
ISSN	0039-6028
DOIs	https://doi.org/10.1016/j.susc.2005.01.024
Publication status	Published - 2005
Externally published	Yes

Keywords

Catalysis
Oxidation
Surface chemical reaction
Silver
Copper
Alkenes

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10.1016/j.susc.2005.01.024

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title = "Copper is highly effective for the epoxidation of a {"}difficult{"} alkene, whereas silver is not",

abstract = "trans-Methyl styrene, an alkene that contains readily abstractable allylic H atoms, adsorbs with very similar conformations on oxygenated single crystal surfaces of Cu and Ag. Strikingly, however, subsequent reaction on silver leads merely to combustion of the organic molecule, whereas copper is extremely effective in catalyzing the epoxidation of this {"}difficult{"} alkene. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "Catalysis, Oxidation, Surface chemical reaction, Silver, Copper, Alkenes",

author = "R.L. Cropley and F.J. Williams and O.P.H. Vaughan and Andrew Urquhart and M.S. Tikhov and R.M. Lambert",

year = "2005",

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volume = "578",

pages = "L85--L88",

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TY - JOUR

T1 - Copper is highly effective for the epoxidation of a "difficult" alkene, whereas silver is not

AU - Cropley, R.L.

AU - Williams, F.J.

AU - Vaughan, O.P.H.

AU - Urquhart, Andrew

AU - Tikhov, M.S.

AU - Lambert, R.M.

PY - 2005

Y1 - 2005

N2 - trans-Methyl styrene, an alkene that contains readily abstractable allylic H atoms, adsorbs with very similar conformations on oxygenated single crystal surfaces of Cu and Ag. Strikingly, however, subsequent reaction on silver leads merely to combustion of the organic molecule, whereas copper is extremely effective in catalyzing the epoxidation of this "difficult" alkene. (c) 2005 Elsevier B.V. All rights reserved.

AB - trans-Methyl styrene, an alkene that contains readily abstractable allylic H atoms, adsorbs with very similar conformations on oxygenated single crystal surfaces of Cu and Ag. Strikingly, however, subsequent reaction on silver leads merely to combustion of the organic molecule, whereas copper is extremely effective in catalyzing the epoxidation of this "difficult" alkene. (c) 2005 Elsevier B.V. All rights reserved.

KW - Catalysis

KW - Oxidation

KW - Surface chemical reaction

KW - Silver

KW - Copper

KW - Alkenes

U2 - 10.1016/j.susc.2005.01.024

DO - 10.1016/j.susc.2005.01.024

M3 - Journal article

VL - 578

SP - L85-L88

JO - Surface Science

JF - Surface Science

SN - 0039-6028

IS - 1-3

ER -