Controlling the Plasma-Polymerization Process of N-Vinyl-2-pyrrolidone

Kion Norrman, Bjørn Winther-Jensen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

N-vinyl-2-pyrrolidone was plasma-polymerized on glass substrates using a pulsed AC plasma. Pulsed AC plasma produces a chemical surface structure different from that produced by conventional RF plasma; this is ascribed to the different power regimes used. A high degree of control over the structure of the chemical surface was obtained using pulsed AC plasma, as shown by ToF-SIMS. It is demonstrated how the experimental conditions to some extent control the chemical structure of the plasma-polymerized film, e.g., film thickness, density of post-plasma-polymerized oligomeric chains, and the density of intact pyrrolidone rings.
Original languageEnglish
JournalPlasma Processes and Polymers
Volume2
Issue number5
Pages (from-to)414-423
ISSN1612-8850
DOIs
Publication statusPublished - 14 Jun 2005

Keywords

  • ATR FT-IR
  • N-vinyl-2-pyrrolidone
  • plasma polymerization
  • poly(vinyl pyrrolidone)
  • ToF-SIMS
  • XPS

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